ppm level supported Pd-catalyzed carbonylative Suzuki-Miyaura cross-coupling of aryl iodides using oxalic acid as CO source

被引：0
作者：
Mehara, Pushkar [1 ,2 ]
Sharma, Poonam [1 ,2 ]
Sharma, Ajay Kumar [1 ,2 ]
Shaifali [1 ,2 ]
Das, Pralay [1 ,2 ]
机构：
[1] CSIR Inst Himalayan Bioresource Technol, Chem Technol Div, Palampur 176061, Himachal Prades, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
MOLECULAR CATALYSIS | 2023年 / 550卷
关键词：
Polystyrene supported palladium; Carbonylative Suzuki coupling reaction; Biaryl ketones; Oxalic acid; FRIEDEL-CRAFTS ACYLATION; ARYLBORONIC ACIDS; PALLADIUM NANOPARTICLES; ATMOSPHERIC-PRESSURE; N-FORMYLSACCHARIN; BIARYL KETONES; EFFICIENT; DERIVATIVES; HALIDES; ACCESS;
D O I：
10.1016/j.mcat.2023.113546
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polystyrene supported palladium (Pd@PS) catalyzed cost-efficient and sustainable protocol for carbonylative Suzuki-Miyaura cross-coupling (C-SMCC) reaction has been reported. Herein, ppm (parts per million) level of Pd (0.1 mol%, 1000 ppm) of the Pd@PS catalyst, with high turnover number, i.e. similar to 5061 (calculated upto six cycles) was applied. Furthermore, to avoid the direct use of toxic, flammable, odorless carbon monoxide (CO) gas, oxalic acid has been applied as solid, inexpensive, additive-free CO source. The developed protocol is applicable to wide range of aryl iodides and phenylboronic acids that produce symmetrical and unsymmetrical biaryl ketones. Interestingly, di-carbonylative Suzuki-Miyaura cross-coupling products were also obtained in moderate to excellent yields.
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页数：9
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