Rational design of Mg(OH)2/Cu2(OH)3(NO3) binary heterostructure electrodes for enriched supercapacitors performance

被引:5
|
作者
Karthigaimuthu, D. [1 ]
Raju, Kumar [2 ]
Chakrabortty, Sabyasachi [3 ]
Ghosh, Siddhartha [4 ]
Arjunkumar, B. [5 ]
Elangovan, T. [1 ]
Sambasivam, Sangaraju [5 ]
机构
[1] Periyar Univ, Dept Energy Sci & Technol, Smart Energy Mat Res Lab SEMRL, Salem 636011, India
[2] Univ Cambridge, Faraday Inst Res Fellow, Inst Mfg IFM, Trinity Ln, Cambridge CB2 1TN, England
[3] SRM Univ AP Andhra Pradesh, Dept Chem, Amaravati 522502, Andhra Pradesh, India
[4] SRM Univ AP Andhra Pradesh, Dept Phys, Amaravati 522502, Andhra Pradesh, India
[5] United Arab Emirates Univ, Natl Water & Energy Ctr, Al Ain 15551, U Arab Emirates
关键词
Binary heterostructure; Mg(OH)(2); Cu-2(OH)(3)(NO3); Energy storage; Electrode; Supercapacitor; OXIDE NANOPARTICLES; COPPER; HYDROXIDE; ADSORPTION; MG(OH)(2); FABRICATION; MORPHOLOGY; NANORODS; ANODE; CUO;
D O I
10.1007/s11581-023-05304-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrode material properties, such as widening the voltage window, rational design, and morphology are known to play an essential role in increasing its efficiency for energy storage devices. Herein, a simple strategy to first prepare a Mg(OH)(2)/Cu-2(OH)(3)(NO3) (MHCNx) binary heterostructure by co-precipitation method. The morphology studies from SEM and HR-TEM analysis revealed that the Mg(OH)(2) and Mg(OH)(2)/Cu-2(OH)(3)(NO3) binary heterostructures show quasi-spherical and nanosheet-like structures. The electrochemical characteristics of as-prepared binary heterostructure electrodes were investigated by a three-electrode system. At a low current density of 5 Ag-1, the specific capacitance of the MHCN-2 achieved 146 Fg(-1). The MHCN-2 electrode displayed capacitance retention of similar to 97% and coulombic efficiency of similar to 96% for 5000 cycles. This study offers a facile and low cost approach for producing novel nanostructures and electrodes for energy storage in binary heterostructure materials.
引用
收藏
页码:369 / 381
页数:13
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