Effect of Temperature and Steam-to-Carbon Monoxide (CO) Ratio on Hydrogen Production in Water-Gas Shift Reaction using Cu-ZnO-Al2O3 Catalyst

被引:2
作者
Desi, Sekar Kumala [1 ]
Nursa'adah, Restu Siti [1 ]
Anindita, Hana Nabila [1 ]
Muharto, Bambang [1 ]
Rahmawati, Nurdiah [1 ]
Rini, Tyas Puspita [1 ]
Rosyadi, Erlan [1 ]
机构
[1] Natl Res & Innovat Indonesia, Convers & Conservat Energy Res Ctr, Bioenergy & Alternat Energy Res Grp, Tangerang Selatan 15314, Indonesia
关键词
Cu-Zn-Al catalyst; CO conversion time; hydrogen production; steam-to-CO molar ratio; water gas shift reaction; PERFORMANCE;
D O I
10.7454/mss.v27i4.2138
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
This study investigates the effect of steam-to-CO molar ratio and temperature on hydrogen production in a water gas shift reaction using a Cu-ZnO-Al2O3 catalyst. Herein, different steam-to-CO molar ratios (1:1, 2:1, and 3:1) and temperatures (200 degrees C, 250 degrees C, and 300 degrees C) were applied to investigate their impact on the reaction and H-2 production. The Cu-ZnOAl2O3 catalyst was characterized by its surface area, pore size distribution, and chemical composition. Moreover, the experimental setup enabled the control of temperature and steam-to-CO molar ratio while monitoring the product gas composition. The results revealed a considerable influence of temperature and steam-to-CO molar ratio on CO conversion efficiency. Notably, the majority of the experiment variations exhibited CO conversion exceeding 90% within 1 min throughout the reaction. Additionally, the highest H-2 composition of 53.10% was reached at 250 degrees C with the steam-to-CO molar ratio of 3:1.
引用
收藏
页码:337 / 344
页数:8
相关论文
共 50 条
[41]   Alloying Pd with Cu boosts hydrogen production via room-temperature electrochemical water-gas shift reaction [J].
Wei, Huifang ;
Liu, Huan ;
Yu, Liang ;
Zhang, Mo ;
Zhang, Yunlong ;
Fan, Jinchang ;
Cui, Xiaoju ;
Deng, Dehui .
NANO ENERGY, 2022, 102
[42]   Optimization of Cobalt Loading in Co-CeO2 Catalyst for the High Temperature Water-Gas Shift Reaction [J].
Lee, Yeol-Lim ;
Jha, Ajay ;
Jang, Won-Jun ;
Shim, Jae-Oh ;
Jeon, Kyung-Won ;
Na, Hyun-Suk ;
Kim, Hak-Min ;
Lee, Da-We ;
Yoo, Seong-Yeun ;
Jeon, Byong-Hun ;
Bae, Jong Wook ;
Roh, Hyun-Seog .
TOPICS IN CATALYSIS, 2017, 60 (9-11) :721-726
[43]   Effect of Ce Doping of a Co/Al2O3 Catalyst on Hydrogen Production via Propane Steam Reforming [J].
Do, Jeong Yeon ;
Chava, Rama Krishna ;
Son, Namgyu ;
Kim, Junyeong ;
Park, No-Kuk ;
Lee, Doyeon ;
Seo, Myung Won ;
Ryu, Ho-Jung ;
Chi, Jun Hwa ;
Kang, Misook .
CATALYSTS, 2018, 8 (10)
[44]   Cu/ZrO2 Catalyst for Low-Temperature Water-Gas Shift Reaction: Preparation, Characterization and Performance [J].
Ruan Chunxiao ;
Chen Chongqi ;
Zhang Yanjie ;
Lin Xingyi ;
Zhan Yingying ;
Zheng Qi .
CHINESE JOURNAL OF CATALYSIS, 2012, 33 (05) :842-849
[45]   Effect of glucose pretreatment on Cu-ZnO-Al2O3 catalyzed CO2 hydrogenation to methanol [J].
Jiang, Xiuyun ;
Yang, Wenbing ;
Song, Hao ;
Ke, Jucang ;
Li, Peng ;
Li, Rui ;
Ma, Qingxiang ;
Sun, Jian ;
Zhao, Tian-Sheng ;
Tsubaki, Noritatsu .
RSC ADVANCES, 2023, 13 (32) :22493-22502
[46]   Preparation of CuO/CeO2 Catalyst with Enhanced Catalytic Performance for Water-Gas Shift Reaction in Hydrogen Production [J].
Chen, Chongqi ;
Zhan, Yingying ;
Li, Dalin ;
Zhang, Yanjie ;
Lin, Xingyi ;
Jiang, Lilong ;
Zheng, Qi .
ENERGY TECHNOLOGY, 2018, 6 (06) :1096-1103
[47]   A highly active and synergistic Pt/Mo2C/Al2O3 catalyst for water-gas shift reaction [J].
Osman, Ahmed I. ;
Abu-Dahrieh, Jehad K. ;
Cherkasov, Nikolay ;
Fernandez-Garcia, Javier ;
Walker, David ;
Walton, Richard I. ;
Rooney, David W. ;
Rebrov, Evgeny .
MOLECULAR CATALYSIS, 2018, 455 :38-47
[48]   An important parameter for synthesis of Al2O3 supported Cu-Zn catalysts in low-temperature water-gas shift reaction under practical reaction condition [J].
Shim, Jae-Oh ;
Na, Hyun-Suk ;
Ahn, Seon-Yong ;
Jeon, Kyung-Won ;
Jang, Won-Jun ;
Jeon, Byong-Hun ;
Roh, Hyun-Seog .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (29) :14853-14860
[49]   Effect of Reaction Temperature and Steam to Carbon Ratio on Hydrogen Production for Steam Reforming of Bio-Ethanol Using the Palladium Membrane Reactor [J].
Kinouchi, Kouji ;
Katoh, Masahiro ;
Nakagawa, Keizo ;
Sugiyama, Shigeru ;
Yoshikawa, Takushi ;
Wada, Mamoru .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2014, 47 (01) :14-20
[50]   Syngas Production from Combined Steam Gasification of Biochar and a Sorption-Enhanced Water-Gas Shift Reaction with the Utilization of CO2 [J].
Chimpae, Supanida ;
Wongsakulphasatch, Suwimol ;
Vivanpatarakij, Supawat ;
Glinrun, Thongchai ;
Wiwatwongwana, Fasai ;
Maneeprakorn, Weerakanya ;
Assabumrungrat, Suttichai .
PROCESSES, 2019, 7 (06)