A zirconium-based metal-organic framework with dibenzothiophene linkers: synthesis, structural analysis, and gas-adsorption properties

被引：4
作者：
Sugamata, Koh [1 ,3 ]
Kobayashi, Sho [1 ]
Amanokura, Natsuki [1 ,2 ]
Shirai, Akihiro [1 ,2 ]
Minoura, Mao [1 ,3 ]
机构：
[1] Rikkyo Univ, Coll Sci, Dept Chem, Toshima, Japan
[2] Nippon Soda Co Ltd, Chiyoda Ku, Tokyo, Japan
[3] Rikkyo Univ, Coll Sci, Dept Chem, Toshima 1718501, Japan
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 76卷 / 16-24期
关键词：
Metal-organic frameworks (MOFs); coordination polymers; gas-adsorption properties; x-ray diffraction analysis; COORDINATION POLYMERS; METHANE; CO2; MOFS; CH4; SELECTIVITY; HKUST-1; STORAGE; DESIGN; N-2;
D O I：
10.1080/00958972.2023.2287970
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A UiO-67-type Zr-based metal-organic framework (MOF) with dibenzothiophene linkers, UiO-67-S, was synthesized using a solvothermal method. The crystal structure of UiO-67-S exhibits the same topological structure as UiO-67 and its derivatives. UiO-67-S shows high thermal stability and excellent permanent porosity. Moreover, its excellent hydrogen storage indicates that the thiophene moiety is suitable for enhancing the hydrogen storage ability of MOFs.
引用
收藏
页码：1817 / 1824
页数：8
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