Multimode Photo-CSTR (Continuous Stirred Tank Reactor) Setup for Heterogeneous Photocatalytic Processes

被引：5
|
作者：
Ali, Rizvi Syed Aal E. [1 ]
Meng, Jiaolong [1 ]
Jiang, Xuefeng [1 ,2 ,3 ]
机构：
[1] East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Mol & Proc Engn, Shanghai 200062, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
来源：
ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2023年 / 28卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Photoreactor design; Photo CSTR; Multiphasicflow; Heterogeneous photocatalysis; CONTINUOUS-FLOW; DEGRADATION;
D O I：
10.1021/acs.oprd.3c00328
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Photocatalysis has been comprehensively applied to diverse valuable chemical transformations. However, photocatalytic processes have encountered obstacles in gaining wide acceptance in industry, primarily due to scale-up challenges, especially in heterogeneous systems involving equivalent amounts of solids. We designed a photo-continuous stirred tank reactor (CSTR) protocol for heterogeneous photocatalytic processes, which is capable of multiphasic processes with excellent adaptability. Furthermore, glass-wool-supported photocatalyst was successfully made, applied, and recycled at least 12 times without any decrease in hydroxylation of phenylboronic acid in reactivity, enabling gram scale synthesis with high efficiency in photo-CSTR.
引用
收藏
页码：1683 / 1689
页数：7
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