Probing the effect of fuel components on the auto-ignition behavior of ammonia/natural gas blends: A case study of ethane addition

Ammonia (NH3) is carbon-free and is known as a promising renewable fuel to achieve carbon reduction and carbon neutrality. However, ammonia presents much lower fuel reactivity compared to hydrocarbon fuels. Thus, ammonia is often blended with high reactivity fuels in practical combustion facilities, and natural gas is a good candidate due to its low carbon emissions and massive reserves. Methane is often used to represent natural gas in previous experimental and simulation studies, while the larger alkanes in natural gas can affect the fuel reactivity of ammonia/natural gas blends. This study aims to explore the effects of fuel components on the auto-ignition behaviors of ammonia/natural gas blends. As methane and ethane are the most important species in natural gas, a blend of 90 % methane and 10 % ethane by volume is used to represent natural gas in this study. A low-pressure shock tube was used to measure the ignition delay times (IDTs) of ammonia/methane, ammonia/ ethane, and ammonia/natural gas blends in 'air' mixtures, with different ammonia blending ratios, at stoi-chiometric condition, at 1 atm and over the temperature range 1200 - 1800 K. The experimental results show that the IDTs of fuel blends increase with ammonia blending ratios. Meanwhile, 10 % ethane in natural gas can influence the fuel reactivity of ammonia/natural gas blends. A detailed kinetic model proposed in our previous study is used to simulate these new IDTs in addition to experimental data available in the literature. Overall, the kinetic model can predict well the auto-ignition behavior of ammonia/methane, ammonia/ethane, and ammonia/natural gas blends over a wide range of experimental conditions. The simulation and sensitivity an-alyses results show that the interaction reaction between ammonia and ethane, C2H6 + NH2 <=> C2H5 + NH3, is important for predicting the fuel reactivity of ammonia/ethane blends below 1600 K at the studied conditions.