Chitosan/MoS2/GO membrane for catalytic degradation of organic contaminants

被引:14
作者
Al Momani, Delal E. [1 ]
Arshad, Fathima [1 ]
Zou, Linda [1 ]
机构
[1] Khalifa Univ Sci & Technol, Dept Civil Infrastruct & Environm Engn, POB 127788, Abu Dhabi 127788, U Arab Emirates
关键词
Nanocomposite membrane; Peroxydase-like nanozyme; MoS2; Chitosan; GO; MOS2; NANOCOMPOSITE; REMOVAL;
D O I
10.1016/j.eti.2023.103410
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Nanocomposite membranes were fabricated by incorporating MoS2 and GO nanomaterials in the chitosan polymer matrix. The higher polymer to nanomaterial ratio resulted in more porous CMG2 membrane than CMG1 membrane. In comparison of the membranes' performance, the control membrane without nanomaterials only had minimal removal of organic matter, whereas both nanocomposite membranes achieved 95-100 % color removal. CMG2 also achieved 100 % TOC removals of MO solutions whereas the TOC removal by CMG1 was less complete. The MoS2 nanoparticles induced catalytic effect to degradate organic matter. The GO nanosheets also introduced a more substantial negative charge to enhance the separation and rejection of organic contaminants. In addition, a faster treatment kinetics per filtration cycle was also displayed by CMG2 than that of CMG1. This was due to its higher posoristy facilitated better access to the MoS2 nanomaterials, for the dye molecules interacting with catalytic sites. Chitosan/MoS2/GO membrane could be a promising membrane-based solution for efficient catalytic degradation of organic contaminants in water and wastewater treatment.
引用
收藏
页数:18
相关论文
共 56 条
[1]   Strategies to improve membrane performance in wastewater treatment [J].
Ahmed, Shams Forruque ;
Mehejabin, Fatema ;
Momtahin, Adiba ;
Tasannum, Nuzaba ;
Faria, Nishat Tasnim ;
Mofijur, M. ;
Anh Tuan Hoang ;
Vo, Dai-Viet N. ;
Mahlia, T. M., I .
CHEMOSPHERE, 2022, 306
[2]  
Al Ansari Z, 2022, ENVIRON SCI-WAT RES, V8, P2694, DOI [10.1039/D2EW00385F, 10.1039/d2ew00385f]
[3]   Strategies for tuning hierarchical porosity of 3D rGO to optimize ion electrosorption [J].
Al Suwaidi, Fatma ;
Younes, Hammad ;
Sreepal, Vishnu ;
Nair, Rahul R. ;
Aubry, Cyril ;
Zou, Linda .
2D MATERIALS, 2019, 6 (04)
[4]   Modification of polyethersulfone ultrafiltration membrane using ultrasonic-assisted functionalized MoS2 for treatment of oil refinery wastewater [J].
Arefi-Oskoui, Samira ;
Khataee, Alireza ;
Safarpour, Mahdie ;
Vatanpour, Vahid .
SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 238
[5]   Highly Permeable MoS2 Nanosheet Porous Membrane for Organic Matter Removal [J].
Arshad, Fathima ;
Aubry, Cyril ;
Zou, Linda .
ACS OMEGA, 2022, 7 (02) :2419-2428
[6]   2D MoS2 nanoplatelets for fouling resistant membrane surface [J].
Arshad, Fathima ;
Aubry, Cyril ;
Ravaux, Florent ;
Zou, Linda .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 590 :415-423
[7]   Improving the performance of heavy metal separation from water using MoS2 membrane: Molecular dynamics simulation [J].
Azamat, Jafar ;
Khataee, Alireza .
COMPUTATIONAL MATERIALS SCIENCE, 2017, 137 :201-207
[8]   MoS2-based nanostructures: synthesis and applications in medicine [J].
Bazaka, Kateryna ;
Levchenko, Igor ;
Lim, Jian Wei Mark ;
Baranov, Oleg ;
Corbella, Carles ;
Xu, Shuyan ;
Keidar, Michael .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2019, 52 (18)
[9]   Development, preparation and characterization of chitosan, gelatin and heparin membranes for biomedical applications [J].
da Silva, Rossana Seixas Maia ;
Barbosa, Rossemberg Cardoso ;
dos Santos Chagas, Camila ;
da Silva, Emerson Barbosa ;
Feder, David ;
Fonseca, Fernando Luiz Affonso ;
Fook, Marcus Vinicius Lia .
SN APPLIED SCIENCES, 2022, 4 (02)
[10]   Enhanced removal of hydrophobic endocrine disrupting compounds from wastewater by nanofiltration membranes intercalated with hydrophilic MoS2 nanosheets: Role of surface properties and internal nanochannels [J].
Dai, Ruobin ;
Han, Hongyi ;
Wang, Tianlin ;
Li, Xuesong ;
Wang, Zhiwei .
JOURNAL OF MEMBRANE SCIENCE, 2021, 628