Preparation of lotus-root-typed TiO2 nanotubes by NH4F/KF based electrolyte and its efficient photocathodic protection for 304 stainless steel

被引:7
作者
Li, Jianmin [1 ]
Wang, Tongtong [1 ]
Yu, Jiahui [1 ]
Gao, Rongjie [1 ]
机构
[1] Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2 nanotube array; Lotus-root-type porous structure; Anodization; Photoelectrochemical; Photocathodic protection;
D O I
10.1016/j.matlet.2023.133941
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A highly ordered lotus-root-typed TiO2 nanotube array (TNTAs) was prepared by two-step electrochemical anodization in a novel NH4F/KF-based electrolyte. The effects of different morphologies of TiO2 nanotubes on the photoelectrochemical properties of TNTAs were studied. The photoelectrochemical properties of TNTAs were evaluated by measuring the photocurrent density-time curve. The photocathodic protection performance of TNTAs on 304 stainless steel was evaluated by measuring open circuit potential and Tafel curve. The results showed that the TNTAs with lotus-root-type porous structures prepared at 20 V had the optimal photoelectric chemical properties and photocathodic protection properties. Under simulated sunlight, the maximum photocurrent density can reach 306.7 mu A center dot cm(-2), and the lowest open circuit potential can reach -0.987 V (vs Ag/AgCl).
引用
收藏
页数:5
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