Dopant-free NiOx Nanocrystals: A Low-cost and Stable Hole Transport Material for Commercializing Perovskite Optoelectronics

被引：52

作者：

Zhang, Hong ^{[1
]}

Zhao, Chenxu ^{[1
,2
]}

Yao, Jianxi ^{[2
]}

Choy, Wallace C. H. ^{[3
]}

机构：

[1] Fudan Univ, Inst Optoelect, Shanghai Frontiers Sci Res Base Intelligent Optoel, Shanghai 200433, Peoples R China

[2] North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewable, Beijing Key Lab Energy Safety & Clean Utilizat, Beijing 102206, Peoples R China

[3] Univ Hong Kong, Dept Elect & Elect Engn, Pokfulam Rd, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2023年 / 62卷 / 24期

关键词：

Chemical Precipitation Method; Hole Transport Material; Nanocrystal; Nickel Oxide; Perovskite Solar Cell; SOLAR-CELLS; HIGH-PERFORMANCE; INTERFACIAL LAYER; EFFICIENT; STABILITY; FILMS; THIN; NANOPARTICLES;

D O I：

10.1002/anie.202219307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Advancing inverted (p-i-n) perovskite solar cells (PSCs) is critical for commercial applications given their compatibility with different bottom cells for tandem photovoltaics, low-temperature processability (<= 100 degrees C), and promising operational stability. Although inverted PSCs have achieved an efficiency of over 25 % using doped or expensive organic hole transport materials (HTMs), their synthesis cost and stability still cannot meet the requirements for their commercialization. Recently, dopant-free and low-cost non-stoichiometric nickel oxide nanocrystals (NiOx NCs) have been extensively studied as a low-cost and effective HTM in perovskite optoelectronics. In this minireview, we summarize the synthesis and surface-functionalization methods of NiOx NCs. Then, the applications of NiOx NCs in other perovskite optoelectronics beyond photovoltaics are discussed. Finally, we provide a perspective for the future development of NiOx NCs for the commercialization of perovskite optoelectronics.

引用

页数：12

共 77 条

[31] CsPbCl3-Cluster-Widened Bandgap and Inhibited Phase Segregation in a Wide-Bandgap Perovskite and its Application to NiOx-Based Perovskite/Silicon Tandem Solar Cells [J].

Li, Renjie ;

Chen, Bingbing ;

Ren, Ningyu ;

Wang, Pengyang ;

Shi, Biao ;

Xu, Qiaojing ;

Zhao, Hua ;

Han, Wei ;

Zhu, Zhao ;

Liu, Jingjing ;

Huang, Qian ;

Zhang, Dekun ;

Zhao, Ying ;

Zhang, Xiaodan .

ADVANCED MATERIALS, 2022, 34 (27)

[32] Constructing heterojunctions by surface sulfidation for efficient inverted perovskite solar cells [J].

Li, Xiaodong ;

Zhang, Wenxiao ;

Guo, Xuemin ;

Lu, Chunyan ;

Wei, Jiyao ;

Fang, Junfeng .

SCIENCE, 2022, 375 (6579) :434-+

[33] Multifunctional Ionic Liquid as an Interfacial Modifier for High- Performance and Stable NiOx-Based Inverted Perovskite Solar Cells [J].

Li, Yahong ;

Song, Jing ;

Zhang, Yang ;

Kong, Tengfei ;

Liu, Xufu ;

Bi, Dongqin .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2022, 13 (45) :10597-10602

[34] Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cells [J].

Li, Zhen ;

Li, Bo ;

Wu, Xin ;

Sheppard, Stephanie A. ;

Zhang, Shoufeng ;

Gao, Danpeng ;

Long, Nicholas J. ;

Zhu, Zonglong .

SCIENCE, 2022, 376 (6591) :416-+

[35] All-perovskite tandem solar cells with improved grain surface passivation [J].

Lin, Renxing ;

Xu, Jian ;

Wei, Mingyang ;

Wang, Yurui ;

Qin, Zhengyuan ;

Liu, Zhou ;

Wu, Jinlong ;

Xiao, Ke ;

Chen, Bin ;

Park, So Min ;

Chen, Gang ;

Atapattu, Harindi R. ;

Graham, Kenneth R. ;

Xu, Jun ;

Zhu, Jia ;

Li, Ludong ;

Zhang, Chunfeng ;

Sargent, Edward H. ;

Tan, Hairen .

NATURE, 2022, 603 (7899) :73-+

[36] Monolithic all-perovskite tandem solar cells with 24.8% efficiency exploiting comproportionation to suppress Sn(II) oxidation in precursor ink [J].

Lin, Renxing ;

Xiao, Ke ;

Qin, Zhengyuan ;

Han, Qiaolei ;

Zhang, Chunfeng ;

Wei, Mingyang ;

Saidaminov, Makhsud I. ;

Gao, Yuan ;

Xu, Jun ;

Xiao, Min ;

Li, Aidong ;

Zhu, Jia ;

Sargent, Edward H. ;

Tan, Hairen .

NATURE ENERGY, 2019, 4 (10) :864-873

[37] Fully Printable Mesoscopic Perovskite Solar Cells with Organic Silane Self-Assembled Monolayer [J].

Liu, Linfeng ;

Mei, Anyi ;

Liu, Tongfa ;

Jiang, Pei ;

Sheng, Yusong ;

Zhang, Lijun ;

Han, Hongwei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (05) :1790-1793

[38] Local nanoscale phase impurities are degradation sites in halide perovskites [J].

Macpherson, Stuart ;

Doherty, Tiarnan A. S. ;

Winchester, Andrew J. ;

Kosar, Sofiia ;

Johnstone, Duncan N. ;

Chiang, Yu-Hsien ;

Galkowski, Krzysztof ;

Anaya, Miguel ;

Frohna, Kyle ;

Iqbal, Affan N. ;

Nagane, Satyawan ;

Roose, Bart ;

Andaji-Garmaroudi, Zahra ;

Orr, Kieran W. P. ;

Parker, Julia E. ;

Midgley, Paul A. ;

Dani, Keshav M. ;

Stranks, Samuel D. .

NATURE, 2022, 607 (7918) :294-+

[39] Modification of NiOx hole transport layers with 4-bromobenzylphosphonic acid and its influence on the performance of lead halide perovskite solar cells [J].

Mangalam, Jimmy ;

Rath, Thomas ;

Weber, Stefan ;

Kunert, Birgit ;

Dimopoulos, Theodoros ;

Fian, Alexander ;

Trimmel, Gregor .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (10) :9602-9611

[40] Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide [J].

Min, Hanul ;

Kim, Maengsuk ;

Lee, Seung-Un ;

Kim, Hyeonwoo ;

Kim, Gwisu ;

Choi, Keunsu ;

Lee, Jun Hee ;

Seok, Sang Il .

SCIENCE, 2019, 366 (6466) :749-+

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