Transition Metal Catalysts Bearing Multidentate Ligands for Efficient and Environmental Benign Oxidations by H2O2

被引：1

作者：

Sappino, Carla ^{[3
,4
]}

Di Stefano, Stefano ^{[3
,4
]}

Lanzalunga, Osvaldo ^{[3
,4
]}

Zonta, Cristiano ^{[1
,2
]}

Licini, Giulia ^{[1
,2
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, Via Marzolo 1, I-35131 Padua, Italy

[2] Univ Padua, CIRCC, Via Marzolo 1, I-35131 Padua, Italy

[3] Univ Roma La Sapienza, Dipartimento Chim, Ple A Moro 5, I-00185 Rome, Italy

[4] CIRCC Interuniv Consortium Chem React & Catalysis, Via Celso Ulpiani 27, I-70126 Bari, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 26卷 / 14期

关键词：

hydrogen peroxide; hydroxylation; oxidations; oxygen-transfer reactions; peroxometallo complexes; transition metals; IRON COMPLEXES; TRIPHENOLATE COMPLEXES; HYDROCARBON OXIDATION; OXYGEN; HYDROXYLATION; PEROXIDE; ALCOHOLS; CHEAP;

D O I：

10.1002/ejic.202200782

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this perspective, two different classes of multidentate ligands (aminotriphenolate and dipyridinimine) and the corresponding metal (Ti, V, Mo, W, Fe) complexes are described. These catalysts can activate efficiently the environmental benign H2O2 oxidant, promoting a wide variety of oxidative processes (sulfoxidations, N-oxidations, epoxidations, haloperoxidation, alcohol oxidation, hydroxylation).

引用

页数：10

共 47 条

[41] Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide [J].