New magnetic nanocomposite Fe3O4@Saponin/Cu(II) as an effective recyclable catalyst for the synthesis of aminoalkylnaphthols via Betti reaction

被引:2
作者
Heidarpour, Majid [1 ]
Kiani, Marziyeh [1 ]
Anaraki-Ardakani, Hossein [2 ]
Rezaei, Parizad [3 ]
Ghaleh, Saeed Parvizi [4 ]
Ahmadi, Reza [5 ]
Maleki, Mohammad [1 ]
机构
[1] Islamic Azad Univ, Dept Chem, Ahvaz Branch, Ahvaz, Iran
[2] Islamic Azad Univ, Dept Chem, Mahshahr Branch, Mahshahr, Iran
[3] Islamic Azad Univ, Dept Chem Engn, Abadan Branch, Abadan, Iran
[4] Sahand Univ Technol, Fac Petr & Nat Gas Engn, Tabriz, Iran
[5] Islamic Azad Univ, Dept Environm Engn, West Tehran Branch, Tehran, Iran
关键词
Green chemistry; Saponin; Three-component; copper(II) chloride; ONE-POT SYNTHESIS; SOLVENT-FREE; REUSABLE CATALYST; NONIONIC SURFACTANT; EFFICIENT SYNTHESIS; BASES; ACID; 1-AMIDOALKYL-2-NAPHTHOLS; NANOPARTICLES; DERIVATIVES;
D O I
10.1016/j.steroids.2022.109170
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this research, a new magnetic nanocomposite Fe3O4@Saponin/Cu(II) based on quillaja saponin was prepared and the catalyst structure was characterized thoroughly using FT-IR, EDS, TGA, XRD, VSM, HR-TEM, SEM, ICP, BET analyzes. The catalyst prepared in the three-component synthesis of several Betti bases, 1-(alpha-aminoalkyl) naphthols, under environmentally friendly conditions was used. The advantage of this reaction is the high ef-ficiency of the products and the short reaction time. Furthermore, Fe3O4@Saponin/Cu(II) nano-catalyst is recoverable magnetically and is reusable for other processes with no reduction in its activity.
引用
收藏
页数:13
相关论文
共 75 条
  • [11] Advances in Magnetic Nanoparticles for Biomedical Applications
    Cardoso, Vanessa Fernandes
    Francesko, Antonio
    Ribeiro, Clarisse
    Banobre-Lopez, Manuel
    Martins, Pedro
    Lanceros-Mendez, Senentxu
    [J]. ADVANCED HEALTHCARE MATERIALS, 2018, 7 (05)
  • [12] DIHYDRO-1,3-OXAZINE DERIVATIVES AND THEIR ANTITUMOR ACTIVITY
    CHYLINSKA, JB
    URBANSKI, T
    MORDARSKI, M
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 1963, 6 (05) : 484 - &
  • [13] Modular Three-Component Synthesis of 4-Aminoquinolines via an Imidoylative Sonogashira/Cyclization Cascade
    Collet, Jurrien W.
    Ackermans, Kelly
    Lambregts, Jeffrey
    Maes, Bert U. W.
    Orru, Romano V. A.
    Ruijter, Eelco
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (02) : 854 - 861
  • [14] Determination of siloxanes in water samples employing graphene oxide/Fe3O4 nanocomposite as sorbent for magnetic solid-phase extraction prior to GC-MS
    Costa dos Reis, Luciana
    Vidal, Lorena
    Canals, Antonio
    [J]. JOURNAL OF SEPARATION SCIENCE, 2018, 41 (22) : 4177 - 4184
  • [15] Iodine catalyzed preparation of amidoalkyl naphthols in solution and under solvent-free conditions
    Das, Biswanath
    Laxminarayana, Keetha
    Ravikanth, B.
    Rao, B. Rama
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 261 (02) : 180 - 183
  • [16] Fe3O4@SiO2@polyionene/Br3- core-shell-shell magnetic nanoparticles: a novel catalyst for the synthesis of imidazole derivatives under solvent-free conditions
    Dezfoolinezhad, Elham
    Ghodrati, Keivan
    Badri, Rashid
    [J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (05) : 4575 - 4587
  • [17] Supported copper triflate as an efficient catalytic system for the synthesis of highly functionalized 2-naphthol Mannich bases under solvent free condition
    Dindulkar, Someshwar D.
    Puranik, Vedavati G.
    Jeong, Yeon Tae
    [J]. TETRAHEDRON LETTERS, 2012, 53 (33) : 4376 - 4380
  • [18] Heterogeneous acid catalysts prepared by immobilization of H3PW12O40 on silica through impregnation and inclusion, applied to the synthesis of 3H-1, 5-benzodiazepines
    Dolores Morales, M.
    Infantes-Molina, Antonia
    Lazaro-Martinez, J. M.
    Romanelli, Gustavo P.
    Pizzio, Luis R.
    Rodriguez-Castellon, Enrique B.
    [J]. MOLECULAR CATALYSIS, 2020, 485 (485)
  • [19] Aqueous suspension of biocompatible reduced graphene oxide- Au NPs composite as an effective recyclable catalyst in a Betti reaction
    Fathalipour, Soghra
    Ataei, Bahareh
    Janati, Fatemeh
    [J]. MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2019, 97 : 356 - 366
  • [20] Pd(0)-guanidine@MCM-41 as efficient and reusable heterogeneous catalyst for C-C coupling reactions
    Filian, Hossein
    Ghorbani-Choghamarani, Arash
    Tahanpesar, Elham
    [J]. JOURNAL OF POROUS MATERIALS, 2019, 26 (04) : 1091 - 1101