Crystal structure of tetrakis(triphenylphosphine)palladium(0)

被引：4

作者：

Sukhikh, Taisiya S. ^{[1
]}

Davydova, Maria P. ^{[1
]}

Artem'ev, Alexander, V ^{[1
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 02期

关键词：

tetrakis(triphenylphosphine)palladium(0); crystal structure; crystal packing; phase purity control; IR spectra; powder X-ray diffraction analysis; PALLADIUM; COMPLEXES; CATALYSIS; SE;

D O I：

10.1016/j.mencom.2023.02.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal structure of widely employed precatalyst [Pd(Ph3P)(4)] is reported. It crystallizes in P-3 space group [a = 19.0828(8) and c = 26.4423(18) A] with six molecules per unit cell. It is demonstrated that the phase purity of this important compound can now be routinely controlled via powder X-ray diffraction analysis.

引用

页码：171 / 173

页数：3

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