A cauliflower-like CoAl-Sal layered double hydroxide electrocatalyst for water oxidation under neutral condition

被引:11
作者
Yu, Li [1 ]
Liang, Qin [1 ]
机构
[1] Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
关键词
Water oxidation; Electrocatalyst; Layered double hydroxide; Neutral condition; NANOSHEETS; ARRAYS; LDH;
D O I
10.1016/j.matlet.2023.134134
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The cauliflower-like CoAl-Sal layered double hydroxide (CoAl-Sal LDH) is synthesized by a hydrothermal method, which is befitting for massive production. By optimizing the electrochemical conditions, it only needs a low overpotential of 420 mV to reach a current density of 50 mA cm-2 for CoAl-Sal LDH catalyst, surpassing most of the LDHs-based OER catalysts currently reported under the same neutral condition. The resulting CoAl-Sal LDH catalyst not only shows noticeable water oxidation ability, but also reveals sturdy catalytic behavior without a disintegration in oxygen evolution reaction throughout 1 h of testing at neutral pH. The commodious preparation procedure and conspicuous electrocatalytic capability show the great charm of CoAl-Sal LDH to supersede the noble metal-based electrocatalysts toward oxygen evolution.
引用
收藏
页数:4
相关论文
共 13 条
[1]   Two-dimensional layered structure-templated synthesis of graphene nanosheets using CoAl-LDH under low carbonization temperature [J].
Cheng, Zhi-Lin ;
Liu, Ying-Ying ;
Cao, Bao-Chong .
MATERIALS LETTERS, 2016, 175 :215-218
[2]   Heterostructure of ultrafine FeOOH nanodots supported on CoAl-layered double hydroxide nanosheets as highly efficient electrocatalyst for water oxidation [J].
Gang, Chuan ;
Chen, Jiayi ;
Chen, Qihao ;
Chen, Yantao .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 600 (594-601) :594-601
[3]   Flexible CoAl LDH@PEDOT Core/Shell Nanoplatelet Array for High-Performance Energy Storage [J].
Han, Jingbin ;
Dou, Yibo ;
Zhao, Jingwen ;
Wei, Min ;
Evans, David G. ;
Duan, Xue .
SMALL, 2013, 9 (01) :98-106
[4]   Novel Cobalt-Iron-Vanadium Layered Double Hydroxide Nanosheet Arrays for Superior Water Oxidation Performance [J].
Hu, Yiming ;
Wang, Zhaolong ;
Liu, Wenjun ;
Xu, Li ;
Guan, Meili ;
Huang, Yunpeng ;
Zhao, Yan ;
Bao, Jian ;
Li, Hua-ming .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (19) :16828-16834
[5]   Layer-by-layer assembly of luminescent multilayer thin films by MMT, anionic chromophores and magnetic CoAl-LDHs nanosheets [J].
Liu, Meitang ;
Wang, Tianlei ;
Ma, Hongwen ;
Fu, Yu ;
Hu, Kunran ;
Guan, Chao .
MATERIALS LETTERS, 2015, 153 :40-43
[6]   Se-Doping Activates FeOOH for Cost-Effective and Efficient Electrochemical Water Oxidation [J].
Niu, Shuai ;
Jiang, Wen-Jie ;
Wei, Zengxi ;
Tang, Tang ;
Ma, Jianmin ;
Hu, Jin-Song ;
Wan, Li-Jun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (17) :7005-7013
[7]   Key thermodynamic characteristics of nucleation on charged and neutral cores of molecular sizes in terms of the gradient density functional theory [J].
Shchekin, A. K. ;
Lebedeva, T. S. ;
Tatyanenko, D. V. .
COLLOID JOURNAL, 2016, 78 (04) :553-565
[8]   Synthesis and identifying the active site of Cu2Se@CoSe nano-composite for enhanced electrocatalytic oxygen evolution [J].
Wang, Xueyuan ;
Zhou, Yan ;
Tuo, Yongxiao ;
Lin, Yan ;
Yan, Youguo ;
Chen, Chen ;
Li, Yanpeng ;
Zhang, Jun .
ELECTROCHIMICA ACTA, 2019, 320
[9]   Colloidal synthesis of high-performance FeSe/CoSe nanocomposites for electrochemical oxygen evolution reaction [J].
Wang, Xueyuan ;
Zhou, Yan ;
Liu, Ming ;
Chen, Chen ;
Zhang, Jun .
ELECTROCHIMICA ACTA, 2019, 297 :197-205
[10]   Cu2S nanorod arrays with coarse surfaces to enhance the electrochemically active surface area for water oxidation [J].
Wang, Yunpeng ;
Ge, Zhenhua ;
Li, Xing ;
Zhao, Jinping ;
Ma, Bo ;
Chen, Yantao .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2020, 567 :308-315