Facile fabrication of bismuth vanadate grafted carbon nanotubes composite for enhanced oxygen evolution reaction

被引:4
作者
Alshgari, Razan A. [1 ]
Shah, Syed Imran Abbas [2 ]
Blouch, Nosheen [3 ,4 ]
Manzoor, Sumaira [2 ]
Nisa, Mehar Un [2 ]
Ashiq, Muhammad Faheem [1 ]
Rehman, Muhammad Yousaf Ur [2 ]
Mohammad, Saikh [1 ]
Ehsan, Muhammad Fahad [3 ,4 ]
机构
[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[2] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[3] Technol Bahauddin Zakariya Univ, Fac Engn, Dept Bldg & Architectural Engn, Multan, Pakistan
[4] Northeastern Univ, Dept Civil & Environm Engn, Boston, MA 02115 USA
关键词
Bismuth vanadate; Carbon nanotubes; Oxygen evolution reaction; Multimetal oxide; Carbon Support; VANADIUM-OXIDE; EFFICIENT; ELECTROCATALYST; BIVO4;
D O I
10.1016/j.jelechem.2024.118025
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The increasing demand of maintainable energy boosts researchers to develop reliable electrocatalysts for enhanced water splitting mechanisms. All the synthesized materials, including CNTs, BiVO4, and BiVO4/CNTs, were characterized utilizing a variety of methodologies to assist the structural, configurational, morphological, and topographical investigations. This work aims to create unique BiVO4/CNTs nanocomposite, which may have higher electrocatalytic activity then previous materials (81 mV dec-1 tafel slope and overpotential of 237 mV at 10 mAcm � 2). The composite exhibits notable qualities, including extended stability lasting up to 100 h, a substantial electrochemically active surface area (ECSA) of 586.5 cm2, minimal charge transfer resistance (Rct) of 1.3 omega, a low onset potential, a reasonably reduced overpotential, and a relatively modest Tafel slope. The synergistic interaction between CNTs and BiVO4 is responsible for electrocatalyst's exceptional catalytic efficiency and unique stability for 100-hour retaining both morphological and structural features, showcasing structural integrity of BiVO4/CNTs nano-composite. The objective of this research is to split water into its component molecules using a nano-composite made, and may also useful for future applications.
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页数:12
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共 47 条
[1]   Tailoring the Ca-doped bismuth ferrite for electrochemical oxygen evolution reaction and photocatalytic activity [J].
Anand, Pandiyarajan ;
Jaihindh, Dhayanantha Prabu ;
Chang, Wen-Ku ;
Fu, Yen-Pei .
APPLIED SURFACE SCIENCE, 2021, 540
[2]   IrO2 Coated on RuO2 as Efficient and Stable Electroactive Nanocatalysts for Electrochemical Water Splitting [J].
Audichon, Thomas ;
Napporn, Teko W. ;
Canaff, Christine ;
Morais, Claudia ;
Comminges, Clement ;
Kokoh, K. Boniface .
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (05) :2562-2573
[3]   Biomimetic [AV-Er2O3-doped δ-Bi2O3]-stacked nanoplates: an efficient electrocatalyst for OER/HER and electrode material for supercapacitor application [J].
Azhar, Sundus ;
Ahmad, Khuram Shahzad ;
Abrahams, Isaac ;
Jaffri, Shaan Bibi ;
Ingsel, Tenzin ;
Gupta, Ram K. ;
Ali, Daoud .
IONICS, 2023, 29 (06) :2485-2500
[4]   A Janus cerium-doped bismuth oxide electrocatalyst for complete water splitting [J].
Aziz, S. K. Tarik ;
Ummekar, Mayuri ;
Karajagi, Imran ;
Riyajuddin, S. K. ;
Siddhartha, K. V. R. ;
Saini, Abhishek ;
Potbhare, Ajay ;
Chaudhary, Ratiram G. ;
Vishal, Vikram ;
Ghosh, Prakash C. ;
Dutta, Arnab .
CELL REPORTS PHYSICAL SCIENCE, 2022, 3 (11)
[5]   Reactive Sputtering of Bismuth Vanadate Photoanodes for Solar Water Splitting [J].
Chen, Le ;
Alarcon-Llado, Esther ;
Hettick, Mark ;
Sharp, Ian D. ;
Lin, Yongjing ;
Javey, Ali ;
Ager, Joel W. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (42) :21635-21642
[6]   Metal decorated carbon nanotubes for electrocatalytic water splitting [J].
Cozzarini, Luca ;
Bertolini, Gabriele ;
Suran-Brunelli, Simone Tommaso ;
Radiuo, Andrea ;
Bracamonte, Maria Victoria ;
Tavagnacco, Claudio ;
Goldoni, Andrea .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (30) :18763-18773
[7]   The role of carbon in fuel cells [J].
Dicks, Andrew L. .
JOURNAL OF POWER SOURCES, 2006, 156 (02) :128-141
[8]   Ni/ Ni3C core- shell nanoparticles encapsulated in N- doped bamboo- like carbon nanotubes towards efficient overall water splitting [J].
Dong, Tao ;
Zhang, Xiao ;
Cao, Yongqiang ;
Chen, Hsueh-Shih ;
Yang, Ping .
INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (04) :1073-1080
[9]   Fe-Doped Ni3C Nanodots in N-Doped Carbon Nanosheets for Efficient Hydrogen-Evolution and Oxygen-Evolution Electrocatalysis [J].
Fan, Haosen ;
Yu, Hong ;
Zhang, Yufei ;
Zheng, Yun ;
Luo, Yubo ;
Dai, Zhengfei ;
Li, Bing ;
Zong, Yun ;
Yan, Qingyu .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (41) :12566-12570
[10]   From Hollow Olive-Shaped BiVO4 to n-p Core-Shell BiVO4@Bi2O3 Microspheres: Controlled Synthesis and Enhanced Visible-Light-Responsive Photocatalytic Properties [J].
Guan, Mei-Li ;
Ma, De-Kun ;
Hu, Sheng-Wei ;
Chen, Yan-Jun ;
Huang, Shao-Ming .
INORGANIC CHEMISTRY, 2011, 50 (03) :800-805