Magnetic Properties and Enhanced Magneto-Caloric Performances by Zn Substitution in the Dy2BaCu1-xZnxO5 (x=0.25, 0.5, 0.75) Oxides

被引：0

作者：

Ying, Jiayu ^{[1
,2
]}

He, Ningzhou ^{[1
,2
]}

Wang, Xin ^{[1
,2
]}

Lu, Chenxi ^{[1
,2
]}

Zhang, Yikun ^{[1
,2
,3
]}

机构：

[1] Hangzhou Dianzi Univ, Key Lab Novel Mat Sensor Zhejiang Prov, Hangzhou 310012, Peoples R China

[2] Hangzhou Dianzi Univ, Sch Elect & Informat, Hangzhou 310012, Peoples R China

[3] Shanghai Univ, State Key Lab Adv Special Steels, Shanghai 200444, Peoples R China

来源：

JOURNAL OF ELECTRONIC MATERIALS | 2023年 / 52卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Dy2BaCu1-xZnxO5; oxides; magneto-caloric performances; rare earths; magnetic phase transition; RE; HO; DY; ACHIEVEMENT; GD;

D O I：

10.1007/s11664-023-10444-4

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Rare earth-based materials with a large magneto-caloric (MC) effect have aroused significant research interest due to their potential application for cryogenic magnetic refrigeration (MR) technology. In this study, the Cu site Zn-substituted Dy2BaCu1-xZnxO5 oxides were synthesized and systematically investigated concerning the structural, magnetic phase transition, and MC properties. All the Dy2BaCu1-xZnxO5 oxides were found to be single-phased with an orthorhombic crystal structure (space group Pnma). With the increase of Zn content in the Dy2BaCu1-xZnxO5 oxides, the magnetic phase transition (MPT) temperature decreases gradually from 12.1 K to 2.1 K and the nature of MPT changes from first-order to second-order type. Moreover, Zn substitution leads to enhanced MC performance. The maximum magnetic entropy changes, temperature-averaged entropy changes with 5 K-lift, and relative cooling powers under the magnetic field change of 0-70 kOe were evaluated to be 8.49 J/kgK, 9.67 J/kgK and 13.23 J/kgK, 8.38 J/kgK, 9.29 J/kgK, and 13.03 J/kgK and 227.43 J/kg, and 283.63 J/kg and 343.04 J/kg for Dy2BaCu0.75Zn0.25O5, Dy2BaCu0.5Zn0.5O5 , and Dy2BaCu0.25Zn0.75O5, respectively. The observed tunable MPT and enhanced MC performances indicate that the present Dy2BaCu1-xZnxO5 oxides have potential for practical cryogenic MR applications.

引用

页码：4793 / 4800

页数：8