Experimental and numerical investigation of methane combustion in a HCCI engine under enriched oxygen conditions

The challenge in the energy transition lies in the intermittent nature of renewable energy, requiring the development of effective storage methods. E-fuels are considered a promising solution, with potential applications to Homogeneous Charge Compression Ignition (HCCI) engines known for their high thermal efficiency and low nitrogen oxide emissions. However, HCCI engines face limitations such as low power density and a narrow operating range. To overcome these issues, oxygen-enriched combustion is proposed, aiming at enhancing the mixture reactivity and expanding the operating range by decreasing the intake temperature. As the potential of the expansion of the operating range has never been investigated, we performed an experimental campaign using a methane-fuelled HCCI engine at variable oxygen fractions in the oxidizer. To further elucidate the effects of oxy-fuel combustion, we also performed a kinetic analysis of the reactions driving the combustion behaviour. It has been experimentally found that increasing the oxygen content in the mixture, up to 90%, has a significant potential to decrease the needed intake temperature (up to 70 degrees C) of the charge to keep the Maximum Pressure Rise Rate (MPRR) below the safety threshold of 8 bar/CAD. Despite the notable IMEP increase achieved, operating the engine at high oxygen content presents significant technical challenges. Therefore, to make HCCI engines competitive with other combustion modes, it is essential to combine oxygen enrichment with additional power density enhancement techniques. The kinetic analysis has highlighted that the mixture is less sensitive to intake temperature changes at higher oxygen percentages (above 50%) and that the rates of the main reactions involved in methane and OH consumption are highly enhanced by oxygen addition.