Impact of zinc ion addition on corrosion of EH40 steel in natural seawater

被引:4
作者
Gao, Yaohua [1 ,2 ,3 ,4 ]
Xu, Ming [1 ,2 ,3 ,4 ]
Wu, Jiajia [1 ,2 ,3 ]
Zhang, Dun [1 ,2 ,3 ]
Zhu, Liyang [1 ,2 ,3 ,4 ]
Sun, Zhihua [1 ,2 ,3 ,4 ]
Li, Ce [1 ,2 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
[2] Qingdao Natl Lab Marine Sci & Technol, Open Studio Marine Corros & Protect, Qingdao, Peoples R China
[3] Chinese Acad Sci, Ctr Ocean Megasci, Qingdao, Peoples R China
[4] Univ Chinese Acad Sci, Coll Marine Sci, Beijing, Peoples R China
来源
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION | 2023年 / 74卷 / 01期
关键词
EH40; steel; microbiological corrosion; natural seawater; zinc ion; WATER; ZNO; CYTOTOXICITY; GROWTH; SEA;
D O I
10.1002/maco.202213325
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zinc ion is a common heavy metal in marine pollution, but its impact on corrosion of steels without passive films in natural seawater is far from being investigated. In this study, the impact of zinc ion addition (1.5 and 15 mmol/L) on corrosion of EH40 steel commonly utilized for building ships and offshore platforms was studied by numerous methods and technologies. It was found that EH40 steel corrosion was inhibited with the addition of zinc ion, and corrosion inhibition efficiency increased with the concentration added. The deposited ZnO and Zn(OH)(2) on the steel surface was believed to hamper electron transfer, thus inhibiting corrosion. Meanwhile, the bactericidal zinc ion and ZnO mitigated the activity of microorganisms in biofilms to reduce the damage caused by microbiologically influenced corrosion. But pitting corrosion was enhanced with a high concentration of zinc ion added due to the inhomogeneity of ZnO layers.
引用
收藏
页码:68 / 78
页数:11
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