Low tar yield and high energy conversion efficiency in a continuous pyrolysis reactor with modified ribbon screw conveyor

被引:2
作者
Unsac, Anil [1 ,4 ]
Okutan, Hasan Can [2 ,3 ]
Karatepe, Nilgun [1 ]
机构
[1] Istanbul Tech Univ, Energy Inst, TR-34469 Istanbul, Turkiye
[2] Istanbul Tech Univ, Dept Chem Engn, TR-34469 Istanbul, Turkiye
[3] Istanbul Tech Univ, Synthet Fuels & Chem Technol Ctr, TR-34469 Istanbul, Turkiye
[4] IET Engn Ltd, TR-41455 Kocaeli, Turkiye
关键词
Continuous pyrolysis; Screw reactor; Low tar; High-temperature pyrolysis; Thermal cracking; HIGH-TEMPERATURE PYROLYSIS; FUEL GAS-PRODUCTION; WET SEWAGE-SLUDGE; AUGER REACTOR; BIO-OIL; INTERMEDIATE PYROLYSIS; CATALYTIC PYROLYSIS; SUSTAINABLE LIQUID; STEAM GASIFICATION; BED REACTOR;
D O I
10.1016/j.ijhydene.2023.11.346
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The high temperature batch and continuous pyrolysis of rice husk, sewage sludge, composite waste, hazelnut and apricot kernel shell were performed at 850 degrees C in a rotating batch reactor and a continuous reactor with a modified ribbon screw conveyor. Batch results were used in the continuous reactor design and comparison. At the continuous pyrolysis experiments, mixing and conveying efficiency of screw and thermal cracking performance of reactor, heated gas line and cyclone were investigated. Each material was fed into the reactor continuously with a feed rate of 4.5 kg/h for 3.5 h, and then the pipelines and reactor were monitored and collected tar and char were analyzed. The mixing unit and uninterrupted heated system showed excellent performance on tar reduction and tar yields were lower than 1.7 % for all materials. Separation of char dust from the gas without tar condensation in a heated cyclone prevented blocking in gas lines. With the secondary reactions syngas energy conversion efficiency for rice husk, sewage sludge, composite waste, hazelnut shell, and apricot kernel shell were 67.76 %, 59.22 %, 76.35 %, 56.96 %, 61.98 % respectively. With the new design with a modified ribbon screw, different types of materials were decomposed with minimum char yield in less than 15 min without mechanical problems. The high capacity of the installed reactor as 1-10 kg/h moved the technology readiness level (TRL) to 5 and set an example for demonstration in operational environment.
引用
收藏
页码:1332 / 1343
页数:12
相关论文
共 66 条
  • [1] Waste tire pyrolysis:: Comparison between fixed bed reactor and moving bed reactor
    Aylon, E.
    Fernandez-Colino, A.
    Navarro, M. V.
    Murillo, R.
    Garcia, T.
    Mastral, A. M.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (12) : 4029 - 4033
  • [2] A Comprehensive Characterization of Pyrolysis Oil from Softwood Barks
    Ben, Haoxi
    Wu, Fengze
    Wu, Zhihong
    Han, Guangting
    Jiang, Wei
    Ragauskas, Arthur J.
    [J]. POLYMERS, 2019, 11 (09)
  • [3] Microwave pyrolysis of microalgae for high syngas production
    Beneroso, D.
    Bermudez, J. M.
    Arenillas, A.
    Menendez, J. A.
    [J]. BIORESOURCE TECHNOLOGY, 2013, 144 : 240 - 246
  • [4] Blanco-Sanchez PH, 2012, 4 INT C ENG WAST BIO
  • [5] Pyrolysis in auger reactors for biochar and bio-oil production: A review
    Brassard, Patrick
    Godbout, Stephane
    Raghavan, Vijaya
    [J]. BIOSYSTEMS ENGINEERING, 2017, 161 : 80 - 92
  • [6] Auger reactors for pyrolysis of biomass and wastes
    Campuzano, Felipe
    Brown, Robert C.
    Daniel Martinez, Juan
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2019, 102 : 372 - 409
  • [7] Pyrolysis characteristics of RDF and HPDE blends with biomass
    Chavando, Jose Antonio Mayoral
    de Matos, Edvenante Claudio Jose
    Silva, Valter Bruno
    Tarelho, Luis A. C.
    Cardoso, Joao Sousa
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (45) : 19901 - 19915
  • [8] Slow Pyrolysis Performance and Energy Balance of Corn Stover in Continuous Pyrolysis-Based Poly-Generation Systems
    Cong, Hongbin
    Masek, Ondrej
    Zhao, Lixin
    Yao, Zonglu
    Meng, Haipo
    Hu, Erfeng
    Ma, Teng
    [J]. ENERGY & FUELS, 2018, 32 (03) : 3743 - 3750
  • [9] Pyrolysis biochar systems, balance between bioenergy and carbon sequestration
    Crombie, Kyle
    Masek, Ondrej
    [J]. GLOBAL CHANGE BIOLOGY BIOENERGY, 2015, 7 (02): : 349 - 361
  • [10] Demonstration of the waste tire pyrolysis process on pilot scale in a continuous auger reactor
    Daniel Martinez, Juan
    Murillo, Ramon
    Garcia, Tomas
    Veses, Alberto
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2013, 261 : 637 - 645