Magnetically Reusable Polymetallic Pd-Catalyst for Sonogashira Reaction in Ionic Liquid

被引：1
作者：
Bumagin, N. A. [1 ]
机构：
[1] Lomonosov Moscow State Univ, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
palladium; magnetite; APTES; Pd-Fe-Co-Ni; Fe3O4@Si-NH2 composites; Sonogashira reaction; ionic liquid; SUZUKI-MIYAURA REACTION; PALLADIUM CATALYSTS; COPPER-FREE; RANEY-NICKEL; LIGAND-FREE; NANOPARTICLES; ARYL; COMPLEXES; HECK;
D O I：
10.1134/S1070363223020147
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Pd-Fe-Co-Ni/Fe3O4@Si-NH2 and Pd-Fe-Co-Ni/Fe3O4@Si-NH2@Pd hybrid materials have been synthesized based on magnetite modified with 3-aminopropyltriethoxysilane (APTES). Due to the synergistic effect, new magnetic polymetallic composites have exhibited high catalytic activity in the Sonogashira reaction in a ionic liquid medium, which makes it possible to perform catalysis efficiently in the presence of 0.5 mol % of palladium. The new catalysts can be easily removed from the reaction mixture using an external magnet and can be used up to 5-6 times without any visible loss of activity.
引用
收藏
页码：332 / 344
页数：13
相关论文
共 58 条
  • [11] Functionalized isoxazole and isothiazole ligands: design, synthesis, palladium complexes, homogeneous and heterogeneous catalysis in aqueous media
    Bumagin, N. A.
    Potkin, V. I.
    [J]. RUSSIAN CHEMICAL BULLETIN, 2016, 65 (02) : 321 - 332
  • [12] Isoxazol-3-yl(Isothiazol-3-yl)-1,2,4-Triazoles, -Tetrazoles, and-1,3,4-Oxadiazoles: Synthesis, Palladium Complexes, and Catalytic Applications
    Bumagin, N. A.
    Petkevich, S. K.
    Kletskov, A. V.
    Livantsov, M. V.
    Golantsov, N. E.
    Potkin, V. I.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2014, 49 (10) : 1515 - 1529
  • [13] BUMAGIN NA, 1984, SYNTHESIS-STUTTGART, P728
  • [14] BUMAGIN NA, 1982, DOKL AKAD NAUK SSSR+, V266, P862
  • [15] BUMAGIN NA, 1984, DOKL AKAD NAUK SSSR+, V274, P1103
  • [16] Effective bimetallic composite catalysts for the synthesis of arylated furans and thiophenes in aqueous media
    Bumagin, Nikolay A.
    Petkevich, Sergey K.
    Kletskov, Alexey V.
    Alekseyev, Roman S.
    Potkin, Vladimir I.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2019, 55 (06) : 508 - 516
  • [17] High-turnover aminopyridine-based Pd-catalysts for Suzuki-Miyaura reaction in aqueous media
    Bumagin, Nikolay A.
    [J]. CATALYSIS COMMUNICATIONS, 2016, 79 : 17 - 20
  • [18] SYNTHESIS OF ARYL-SUBSTITUTED AND VINYL-SUBSTITUTED ACETYLENE DERIVATIVES BY USE OF NICKEL AND PALLADIUM COMPLEXES
    CASSAR, L
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 93 (02) : 253 - 257
  • [19] Pd-Catalyzed decarboxylative alkynylation of alkynyl carboxylic acids with arylsulfonyl hydrazides via a desulfinative process
    Chang, Sheng
    Liu, Ying
    Yin, Shu Zhu
    Dong, Lin Lin
    Wang, Jian Feng
    [J]. NEW JOURNAL OF CHEMISTRY, 2019, 43 (14) : 5357 - 5362
  • [20] Application of Bimetallic and Trimetallic Nanoparticles Supported on Graphene as novel Heterogeneous Catalysts in the Reduction of Nitroarenes, Homo-coupling, Suzuki-Miyaura and Sonogashira Reactions
    Chopani, Seyede Mandiye Hoseini
    Asadi, Shima
    Heravi, Majid M.
    [J]. CURRENT ORGANIC CHEMISTRY, 2020, 24 (19) : 2216 - 2234
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