MXene as emerging material for photocatalytic degradation of environmental pollutants

被引:146
作者
Solangi, Nadeem Hussain [1 ]
Karri, Rama Rao [2 ]
Mazari, Shaukat Ali [1 ]
Mubarak, Nabisab Mujawar [2 ]
Jatoi, Abdul Sattar [1 ]
Malafaia, Guilherme [3 ,4 ,5 ]
Azad, Abul Kalam [6 ]
机构
[1] Dawood Univ Engn & Technol, Dept Chem Engn, Karachi 74800, Pakistan
[2] Univ Teknol Brunei, Fac Engn, Petr & Chem Engn, BE-1410 Bandar Seri Begawan, Brunei
[3] Goiano Fed Inst, Postgrad Program Conservat Cerrado Nat Resources, Urutai, GO, Brazil
[4] Univ Fed Uberlandia, Postgrad Program Ecol Conservat & Biodivers, Uberlandia, MG, Brazil
[5] Univ Fed Goias, Postgrad Program Biotechnol & Biodivers, Goiania, GO, Brazil
[6] Univ Brunei Darussalam, Fac Integrated Technol, Jalan Tungku Link, BE-1410 Gadong, Brunei
关键词
MXene; Photocatalyst; Photocatalytic degradation; Emerging pollutants; Decontamination; Dyes; Heavy metal; CO2; reduction; 2-DIMENSIONAL TITANIUM CARBIDE; TRANSITION-METAL CARBIDES; METHYL-ORANGE ADSORPTION; ONE-STEP SYNTHESIS; CONGO-RED; TI3C2; MXENE; COMPOSITE PHOTOCATALYST; FACILE SYNTHESIS; WATER-TREATMENT; QUANTUM DOTS;
D O I
10.1016/j.ccr.2022.214965
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In recent years, MXene has attracted significant interest in the photocatalysis because of its novel physi-cal and chemical characteristics, including uniform planer structure, strong metallic conductivity, effec-tive functional groups and plenty of derivatives. Compared to other photocatalysts for the photocatalytic degradation of various contaminants, MXene-based photocatalysts possess excellent photodegradation performance and long-term stability. MXene is widely used as a photocatalyst for the photodegradation of organic compounds and CO2 conversion into value-added products to remediate the environment. MXene-based composites possess superb photodegradation activity compared to the pristine MXene because it lacks the active sites and porous structure compared to MXene-based composites. For exam-ple, the NiFe/MXene nanocomposite has ability to degrade the targeted the organic contaminants 4 and 6.72 times higher than the pristine MXene and NiFe, respectively. MXene and their derivatives are invalu-able photocatalysts because of their widespread accessibility, inexpensiveness, non-irritating nature, and excellent photocatalytic performance. The active functional groups present on the surface of MXene have a viable impact on the photodegradation performance. This study reports the recent investigations on the photodegradation capability of MXene-based photocatalysts. The physiochemical characteristics of MXene have been discussed briefly for an extensive understanding of the activity of MXene-based photo-catalysts. The strength of MXene-based photocatalysts for the photodegradation of organic compounds and CO2 conversion into value-added products, physical and chemical synthesis routes of MXene pre-paration are reviewed. Finally, the future work and challenges faced by MXene-based photocatalysts are presented.(c) 2022 Elsevier B.V. All rights reserved.
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页数:40
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