GaN/rGO nanocomposite gas sensor for enhanced NH3 sensing performances at room temperature

被引:26
作者
Li, Donghui [1 ,2 ]
Han, Dan [1 ,2 ]
Chen, Yi [1 ,2 ,5 ]
Hong, Yutao [1 ,2 ,5 ]
Duan, Qi [1 ,2 ,5 ]
Wang, Hongtao [1 ,2 ]
He, Xiuli [3 ]
Zhao, Li [4 ]
Wang, Weidong [4 ]
Sang, Shengbo [1 ,2 ]
机构
[1] Taiyuan Univ Technol, Coll Elect Informat & Opt Engn, Shanxi Key Lab Micro Nano Sensors & Artificial Int, Taiyuan 030024, Peoples R China
[2] Taiyuan Univ Technol, Key Lab Adv Transducers & Intelligent Control Syst, Minist Educ, Taiyuan 030024, Peoples R China
[3] Chinese Acad Sci, State Key Lab Transducer Technol, Aerosp Informat Res Inst, Beijing 100190, Peoples R China
[4] Chinese Peoples Liberat Army Gen Hosp, Bioengn Res Ctr, Med Innovat Res Div, Beijing, Peoples R China
[5] Shanxi Res Inst 6D Artificial Intelligence Biomed, Taiyuan 030024, Peoples R China
基金
中国国家自然科学基金;
关键词
GaN/rGO; Nanocomposite; NH3 gas sensor; Room temperature; GRAPHENE OXIDE; ZNO; AMMONIA; NANOPARTICLES; NANORODS;
D O I
10.1016/j.snb.2023.135209
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, we developed a high -performance NH3 sensor based on GaN/rGO nanocomposites via a low-cost solvothermal method and subsequent nitridation process. The morphological, structural, and chemical compositions were investigated to demonstrate that GaN and rGO were coupled together by interfacial modulation, and the GaN/rGO heterostructure chemical bonds are successfully formed. Gas-sensing performance test results show that the fabricated GaN/rGO (2.2 wt%) NH3 sensor exhibited a high response value (92%), fast response time (11 s), and low limit of detection (500 ppb) at room temperature. In addition, reproducibility, humidity, and long -term stability tests of the GaN/rGO sensor were also conducted in this work. The enhancement sensing mechanisms are attributed to the large specific surface area, the excellent conductivity of rGO, and resistance modulation effect of the heterojunction potential. Hence, the GaN/rGO gas sensor can be regarded as a promising sensing solution for atmospheric and exhaled NH3 detection at room temperature.
引用
收藏
页数:10
相关论文
共 46 条
[31]   H2, H2S gas sensing properties of rGO/GaN nanorods at room temperature: Effect of UV illumination [J].
Reddeppa, Maddaka ;
Park, Byung-Guon ;
Kim, Moon-Deock ;
Peta, Koteswara Rao ;
Nguyen Du Chinh ;
Kim, Dojin ;
Kim, Song-Gang ;
Murali, G. .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 264 :353-362
[32]   Breath analysis by nanostructured metal oxides as chemo-resistive gas sensors [J].
Righettoni, Marco ;
Amann, Anton ;
Pratsinis, Sotiris E. .
MATERIALS TODAY, 2015, 18 (03) :163-171
[33]   Fabrication and Characteristics of GaN-Based Light-Emitting Diodes with a Reduced Graphene Oxide Current-Spreading Layer [J].
Ryu, Beo Deul ;
Han, Min ;
Han, Nam ;
Park, Young Jae ;
Ko, Kang Bok ;
Lim, Tae Hyun ;
Chandramohan, S. ;
Cuong, Tran Viet ;
Choi, Chel-Jong ;
Cho, Jaehee ;
Hong, Chang-Hee .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) :22451-22456
[34]   NH3 sensing with self-assembled ZnO-nanowire μHP sensors in isothermal and temperature-pulsed mode [J].
Shao, F. ;
Fan, J. D. ;
Hernandez-Ramirez, F. ;
Fabrega, C. ;
Andreu, T. ;
Cabot, A. ;
Prades, J. D. ;
Lopez, N. ;
Udrea, F. ;
De Luca, A. ;
Ali, S. Z. ;
Morante, J. R. .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 226 :110-117
[35]   High performance ammonia gas sensor based on GaN honeycomb nanonetwork [J].
Shen, Bowei ;
Li, Fu ;
Xie, Yizhu ;
Luo, Jingting ;
Fan, Ping ;
Zhong, Aihua .
SENSORS AND ACTUATORS A-PHYSICAL, 2020, 312
[36]   Selective ppb-level ozone gas sensor based on hierarchical branch-like In2O3 nanostructure [J].
Sui, Ning ;
Zhang, Peng ;
Zhou, Tingting ;
Zhang, Tong .
SENSORS AND ACTUATORS B-CHEMICAL, 2021, 336 (336)
[37]   An ammonia sensor composed of polypyrrole synthesized on reduced graphene oxide by electropolymerization [J].
Tang, Xiaohui ;
Raskin, Jean-Pierre ;
Kryvutsa, Nadzeya ;
Hermans, Sophie ;
Slobodian, Oleksandr ;
Nazarov, Alexei N. ;
Debliquy, Marc .
SENSORS AND ACTUATORS B-CHEMICAL, 2020, 305
[38]   Pt/MoS2/Polyaniline Nanocomposite as a Highly Effective Room Temperature Flexible Gas Sensor for Ammonia Detection [J].
Tian, Xu ;
Cui, Xiuxiu ;
Xiao, Yawei ;
Chen, Ting ;
Xiao, Xuechun ;
Wang, Yude .
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (07) :9604-9617
[39]   Graphene materials as a superior platform for advanced sensing strategies against gaseous ammonia [J].
Vikrant, Kumar ;
Kumar, Vanish ;
Kim, Ki-Hyun .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (45) :22391-22410
[40]  
Wang M, 2023, Adv. Funct. Mater, V33