Effect of Chloride, Sulfate, and Ferrate Salts on Electronic Energy Levels of Anthracene Proving it a Potential Candidate as an ON and ON-OFF UV-Vis Sensor

被引：2
作者：
Kausar, Zakia [1 ]
Mansha, Asim [2 ]
Asim, Sadia [1 ]
机构：
[1] Govt Coll Women Univ, Dept Chem, Faisalabad, Pakistan
[2] Govt Coll Univ, Dept Chem, Faisalabad, Pakistan
来源：
JOURNAL OF FLUORESCENCE | 2024年 / 34卷 / 03期
关键词：
Solvatochromic shifts; HOMO-LUMO gap; Hyperchromic shifts; Ultraviolet-visible sensors; Fluorescence sensors; Intermolecular charge transfer; Non-fluorescent dimers; 5-AMINO-2-MERCAPTO BENZIMIDAZOLE; PHOTOPHYSICAL PROPERTIES; FLUORESCENCE; DERIVATIVES; NANOPARTICLES; DYE; ZNO; DFT;
D O I：
10.1007/s10895-023-03363-4
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Anthracene molecule possesses remarkable optical activity and till today this molecule is of special interest of scientists. Present study is focused on the study of effects of Chloride, Sulfate, Nitrate and Ferrate salts on absorption and emission spectra of targeted fluorophore in carbontetrachloride, chloroform, dichloromethane and methanol. Prominent solvatochromic effects shows dependence of HOMO-LUMO orbitals on solvent polarity. Anthracene molecules exhibits changes in absorption and emission spectra, and show both ON and ON-OFF behavior on addition of said ions. Based on experimental results it was concluded that fluorophore molecule could be used more effectively as UV-Visible (UV-V) sensors in comparison to the emission sensor.
引用
收藏
页码：1365 / 1378
页数：14
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