Organocatalysis for the Chemical Fixation of Carbon Dioxide to Synthesise N-Heterocycles

被引：4

作者：

Esteves, Henrique ^{[1
]}

Costa, Nathalia Evelyn Morais ^{[1
]}

Tomazett, Vinicius Kalil ^{[2
]}

Milani, Jorge Luiz Sonego ^{[3
]}

das Chagas, Rafael Pavao ^{[2
]}

de Fatima, Angelo ^{[1
]}

机构：

[1] Univ Fed Minas Gerais UFMG, Dept Quim, Inst Ciencias Exatas, Belo Horizonte, MG, Brazil

[2] Univ Fed Goias UFG, Inst Quim, Goiania, GO, Brazil

[3] Univ Fed Juiz De Fora UFJF, Dept Quim, Inst Ciencias Exatas, Juiz De Fora, MG, Brazil

来源：

CURRENT GREEN CHEMISTRY | 2024年 / 11卷 / 02期

关键词：

Carbon dioxide; organocatalysis; N-heterocycles; cyclic carbamates; cyclic ureas; benzimidazoles; oxazolidinones; quinazolinediones; benzothiazoles; CATALYZED CARBOXYLATIVE CYCLIZATION; AMINE FUNCTIONALIZED MCM-41; ONE-POT SYNTHESIS; IONIC-LIQUID; EFFICIENT SYNTHESIS; CYCLIC UREAS; CO2; CONVERSION; OXIDATIVE CARBONYLATION; OXAZOLIDINONE SYNTHESIS; STRAIGHTFORWARD ROUTE;

D O I：

10.2174/0122133461255437230930182648

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organocatalysed reactions are becoming powerful tools in the construction of complex molecular skeletons. It gains extra importance when used as a chemical approach to the chemical fixation of carbon dioxide (CO2). Carbon dioxide is an increasingly dangerous environmental hazard as the global climate temperature rises through the greenhouse effect. Meanwhile, in the past decades, significant advances can be noted in the use of organocatalysis for CO2 capture and its conversion into valuable chemicals. Therefore, herein we review a full set of organocatalysts used in CO2 fixation for the synthesis of N-heterocycles since they are present in several chemical structures with biological relevance.

引用

页码：87 / 126

页数：40

共 50 条

[41] Advances in Green Catalysis for the Synthesis of Medicinally Relevant N-Heterocycles
Santos, A. Sofia
Raydan, Daniel
Cunha, Jose C.
Viduedo, Nuno
Silva, Artur M. S.
Marques, M. Manuel B.
CATALYSTS, 2021, 11 (09)
[42] REVIEW ON THE SYNTHESIS OF SIX-MEMBERED N,N-HETEROCYCLES BY MICROWAVE IRRADIATION
Kaur, Navjeet
SYNTHETIC COMMUNICATIONS, 2015, 45 (10) : 1145 - 1182
[43] DEAMINOCYCLIZATION OF DIETHYLENETRIAMINE TO N-HETEROCYCLES OVER ZEOLITES
SRINIVAS, B
KULKARNI, SJ
SUBRAHMANYAM, M
RAO, AVR
ZEOLITES, 1995, 15 (07): : 660 - 662
[44] Chemical Fixation of Carbon Dioxide by Heterogeneous Porous Catalysts
Chowdhury, Ipsita Hazra
Chowdhury, Arpita Hazra
Sarkar, Priyanka
Islam, Sk. Manirul
CHEMNANOMAT, 2021, 7 (06) : 580 - 591
[45] Acceptorless Dehydrogenation of N-Heterocycles in a Photoelectrochemical Cell
Qiao, Kaikai
Liu, Guoquan
Xie, Xinpeng
Liu, Yunfei
Jiang, Wenfeng
Li, Fei
Shi, Lei
ACS CATALYSIS, 2023, 13 (22): : 14763 - 14769
[46] A Comprehensive Review of N-Heterocycles as Cytotoxic Agents
Kumar, Dinesh
Jain, Subheet Kumar
CURRENT MEDICINAL CHEMISTRY, 2016, 23 (38) : 4338 - 4394
[47] The use of benzil to obtain functionalized N-heterocycles
Braibante, Mara E. E.
Braibante, Hugo T. S.
Uliana, Marciana R.
Costa, Carla C.
Spenazzatto, Marcelo
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2008, 19 (05) : 909 - 913
[48] N-Heterocycles via oxidative intramolecular cyclization
Shainyan, Bagrat A.
RUSSIAN CHEMICAL REVIEWS, 2022, 91 (09)
[49] Supported Metal Catalysts for the Synthesis of N-Heterocycles
Aronica, Laura Antonella
Albano, Gianluigi
CATALYSTS, 2022, 12 (01)
[50] Stereoselectively fluorinated N-heterocycles: a brief survey
Hu, Xiang-Guo
Hunter, Luke
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2013, 9 : 2696 - 2708

← 1 2 3 4 5 →