The effect of Lewis acidity of tin loading siliceous MCM-41 on glucose conversion into 5-hydroxymethylfurfural

被引:19
作者
Fang, Juan [1 ]
Dong, Hao [1 ]
Xu, Haimei [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
关键词
Glucose; 5-hydroxymethylfurfural; Lewis acid sites; Tin loading; Mesoporous molecular sieve; MICROWAVE-ASSISTED CONVERSION; CATALYTIC CONVERSION; FRUCTOSE CONVERSION; MESOPOROUS SILICA; DEHYDRATION; BIOMASS; NANOPARTICLES; PERFORMANCE; OXIDATION; SITES;
D O I
10.1016/j.renene.2023.119305
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
5-hydroxymethylfurfural (HMF) is a carbon-neutral feedstock to produce liquid fuels and fine chemicals. HMF can be produced from glucose using solid-acid catalysts via a tandem reaction mechanism involving glucose isomerization to fructose on Lewis acid sites (LAS) and subsequent dehydration to HMF on Bronsted acid sites (BAS). However, few studies have reported HMF production from glucose over LAS. To address this research gap, we designed a series of LAS-dominant tin (Sn) loading mesoporous siliceous MCM-41 molecular sieve (xSn/ MCM) for efficient glucose conversion. The study found that the density of LAS plays a crucial role in glucose conversion, and the highest HMF selectivity was achieved using the catalyst with the highest LAS density (2.2Sn/ MCM). The produced HMF can be further dehydrated into levulinic acid (LA) on LAS or converted into a series of HMF derivatives due to the redox performance of SnO2 formed on catalysts. The highest HMF yield was achieved through an equilibrium of HMF formation and conversion, with approximately 70% selectivity of HMF and HMF-derivatives achieved with near 100% glucose conversion over 2.2Sn/MCM at 150 degrees C for 3 h. Furthermore, the possible reaction pathway of glucose conversion on the xSn/MCM catalyst was elucidated.
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页数:10
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共 49 条
[1]   Pyridine and ammonia as probes for FTIR analysis of solid acid catalysts [J].
Barzetti, T ;
Selli, E ;
Moscotti, D ;
Forni, L .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (08) :1401-1407
[2]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[3]   Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently [J].
Bermejo-Deval, Ricardo ;
Gounder, Rajamani ;
Davis, Mark E. .
ACS CATALYSIS, 2012, 2 (12) :2705-2713
[4]   Synthesis and multi-technique characterization of nickel loaded MCM-41 as potential hydrogen-storage materials [J].
Carraro, P. ;
Elias, V. ;
Garcia Blanco, A. ;
Sapag, K. ;
Moreno, S. ;
Oliva, M. ;
Eimer, G. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 191 :103-111
[5]   Insights into the Interplay of Lewis and Bronsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media [J].
Choudhary, Vinit ;
Mushrif, Samir H. ;
Ho, Christopher ;
Anderko, Andrzej ;
Nikolakis, Vladimiros ;
Marinkovic, Nebojsa S. ;
Frenkel, Anatoly I. ;
Sandler, Stanley I. ;
Vlachos, Dionisios G. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (10) :3997-4006
[6]   Microwave assisted conversion of carbohydrates and biopolymers to 5-hydroxymethylfurfural with aluminium chloride catalyst in water [J].
De, Sudipta ;
Dutta, Saikat ;
Saha, Basudeb .
GREEN CHEMISTRY, 2011, 13 (10) :2859-2868
[7]   An Inner-/Outer-Sphere Stabilized Sn Active Site in β-Zeolite: Spectroscopic Evidence and Kinetic Consequences [J].
Dijkmans, Jan ;
Dusselier, Michiel ;
Janssens, Wout ;
Trekels, Maarten ;
Vantomme, Andre ;
Breynaert, Eric ;
Kirschhock, Christine ;
Sels, Bert F. .
ACS CATALYSIS, 2016, 6 (01) :31-46
[8]   Hierarchically porous titanium phosphate nanoparticles: an efficient solid acid catalyst for microwave assisted conversion of biomass and carbohydrates into 5-hydroxymethylfurfural [J].
Dutta, Arghya ;
Patra, Astam K. ;
Dutta, Saikat ;
Saha, Basudeb ;
Bhaumik, Asim .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (28) :14094-14100
[9]   Nitrogen-doped carbon-decorated copper catalyst for highly efficient transfer hydrogenolysis of 5-hydroxymethylfurfural to convertibly produce 2,5-dimethylfuran or 2,5-dimethyltetrahydrofuran [J].
Gao, Zhi ;
Li, Chenyue ;
Fan, Guoli ;
Yang, Lan ;
Li, Feng .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 226 :523-533
[10]   One-pot transformation of glucose into hydroxymethyl furfural in water over Pd decorated acidic ZrO2 [J].
Goyal, Reena ;
Abraham, B. Moses ;
Singh, Omvir ;
Sameer, Siddharth ;
Bal, Rajaram ;
Mondal, Prasenjit .
RENEWABLE ENERGY, 2022, 183 :791-801