HAT-Mediated Electrochemical Cross Dehydrogenative Coupling Reaction of Quinoxalin-2(1H)-ones with Ethers

被引：5

作者：

Li, Heng ^{[1
]}

Qiang, Congcong ^{[1
]}

Liao, Yujie ^{[1
]}

Chu, Qiao ^{[1
]}

Liu, Ping ^{[1
]}

Sun, Peipei ^{[1
]}

机构：

[1] Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Prov Key Lab Mat Cycle Proc & Pollut Contr, Nanjing 210023, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 18期

基金：

中国国家自然科学基金;

关键词：

Electrochemical oxidation; hydrogen atom transfer; cross dehydrogenative coupling; quinoxalin-2(1H)-ones; ethers; C-H FUNCTIONALIZATION; C(SP(3))-H BONDS; HYDROGEN-ATOM; PHOTOREDOX; ELECTROSYNTHESIS; HETEROARENES; ALKYLATION; ACTIVATION;

D O I：

10.1002/adsc.202300644

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Herein, a method about hydrogen atom transfer (HAT) mediated electrochemical cross dehydrogenative coupling (CDC) reaction of heterocycles with ethers has been established. Saturated linear, branched or cyclic ethers were all suitable for this cross-coupling reaction to form the corresponding products in 70-98% yields. The advantages of this reaction are transition metal- and chemical oxidant-free conditions, high yields, and broad functional group tolerance, etc.

引用

页码：3149 / 3154

页数：6

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