Photoinduced palladium-catalyzed asymmetric allylic C-H amination

被引：6

作者：

Wei, Yi ^{[1
]}

Xiong, Fen-Ya ^{[1
]}

Lu, Liang-Qiu ^{[1
,2
]}

Xiao, Wen-Jing ^{[1
]}

机构：

[1] Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China

[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

来源：

CHEM | 2023年 / 9卷 / 03期

基金：

中国国家自然科学基金;

关键词：

TERMINAL ALKENES; AMINES;

D O I：

10.1016/j.chempr.2023.02.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct allylic C-H amination of alkenes, especially internal ones, with aliphatic amines remains a major challenge in chemical synthesis. Recently in Science, Gevorgyan et al. reported a robust strategy for this process with photoinduced palladium catalysis, which accommodates different olefin substitution patterns and offers excellent selectivities.

引用

页码：559 / 561

页数：3

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