Photoinduced palladium-catalyzed asymmetric allylic C-H amination

被引：3
|
作者：
Wei, Yi [1 ]
Xiong, Fen-Ya [1 ]
Lu, Liang-Qiu [1 ,2 ]
Xiao, Wen-Jing [1 ]
机构：
[1] Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
来源：
CHEM | 2023年 / 9卷 / 03期
基金：
中国国家自然科学基金;
关键词：
TERMINAL ALKENES; AMINES;
D O I：
10.1016/j.chempr.2023.02.007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The direct allylic C-H amination of alkenes, especially internal ones, with aliphatic amines remains a major challenge in chemical synthesis. Recently in Science, Gevorgyan et al. reported a robust strategy for this process with photoinduced palladium catalysis, which accommodates different olefin substitution patterns and offers excellent selectivities.
引用
收藏
页码：559 / 561
页数：3
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