Enhanced flexibility and ablative performance of silicone rubber by constructing an interpenetrating zirconium-containing polysiloxane double network

被引:17
作者
Tian, Jinfeng [1 ]
Yan, Liwei [1 ]
Zhang, Hao [1 ]
Wang, Yuan [1 ]
Cai, Yuanbo [1 ]
Huang, Yisen [1 ]
Lu, Zhaohui [1 ]
Xia, Shuang [1 ]
Chen, Yang [1 ]
Heng, Zhengguang [1 ]
Zou, Huawei [1 ]
Liang, Mei [1 ]
机构
[1] Sichuan Univ, State Key Lab Polymer Mat Engn, Polymer Res Inst, Chengdu 610065, Peoples R China
关键词
Silicone rubber; Zirconium; Ablation resistance; Double network; HEAT SHIELDING MATERIALS; THERMAL INSULATION; COMPOSITES; POLYDIMETHYLSILOXANE; CERAMIZATION; RESISTANCE; BEHAVIOR; SURFACE; ZR;
D O I
10.1016/j.polymer.2023.125749
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
To achieve uniform distribution of heteroatoms in silicone rubber, further simultaneously improving the flexi-bility and ablation resistance, polydimethylsiloxane with an interpenetrating zirconium-containing double-network (Zr-PDMS) was prepared. Compared to pure PDMS, the tensile strength and elongation-at-break of Zr-PDMS with interpenetrating double-network were increased by 615.33% and 124.23%, respectively, exhibiting significantly enhanced flexibility. Ablation analysis indicated that Zr-PDMS showed excellent anti-ablation performance, exhibiting obviously decreased mass ablation rate and charring rate. Most importantly, different from the crisp charred layers of pure PDMS as well as ZrO2 blends, Zr-PDMS formed stable and coherent charred layers after ablation tests. The improvement correlated to the in-situ formation of tetragonal ZrO2 in the char layer of Zr-PDMS, which could avoid the generation of defects in the ZrO2 blends char layer were discussed in detail. This work provided a new strategy of high flexible silicon rubber with excellent ablative performance, which can be expected to be well applied in the hypersonic spacecrafts.
引用
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页数:11
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