Soya bean derived activated carbon as an efficient adsorbent for capture of valuable heavy metals from waste aqueous solution

被引:5
作者
Masoud, Ahmed M. [1 ]
El-Zahhar, Adel A. [3 ,4 ]
El Naggar, Ahmed M. A. [2 ]
Zahran, Asmaa, I [2 ]
Al-Hazmi, Gamil A. A. [3 ]
Taha, Mohamed H. [1 ]
机构
[1] Nucl Mat Author, POB 530, Cairo, Egypt
[2] Egyptian Petr Res Inst EPRI, 1 Ahmed El Zomer St, Cairo, Egypt
[3] King Khalid Univ, Fac Sci, Dept Chem, Abha 9004, Saudi Arabia
[4] AEA, Nucl Chem Dept, Hot Lab Ctr, PO 13759, Cairo, Egypt
关键词
activated carbon; biomass; decontamination; heavy metals; wastewater; ORGANIC POLLUTANTS; URANIUM SORPTION; ADSORPTION; KINETICS; ACID; REMOVAL; VI;
D O I
10.1515/ract-2022-0098
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The removal of hazardous metal ions from liquid waste effluents is very important for water as well as environmental safety. In this regard, this article discusses in detail the U(VI) uptake from aquatic environment using biomass-based Soya Bean activated carbon (labeled as AC-SB). XRD, SEM, FTIR, Raman, and BET analysis were used to characterize the synthesized AC-SB sorbent. Batch-type experiments were used to investigate the effect of various parameters on adsorption efficiency, including pH, metal-ion concentration, temperature, and contact time. The sorption experimental data have been described well with pseudo-second-order kinetic mathematical equations. The equilibrium state of the uptake reaction was 120 min. The Langmuir isotherm model accurately described the equilibrium process which declares that the uranium sorption is a monolayer and homogeneous process. The sorption capacity of the prepared AC was 32.7 mg g(-1). Thermodynamic analysis explore that the U(VI) uptake process is endothermic, feasible and spontenous process. The displayed results demonstrate that the prepared AC-SB sorbent could be used as the proper material for uranium sorption from real matrix samples.
引用
收藏
页码:105 / 115
页数:11
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