An easy-built Halbach magnet for LF-NMR with high homogeneity using optimized target-field passive shimming method

被引:4
作者
Yang, Lize [1 ,2 ]
Chen, Fang [1 ,2 ]
Chen, Li [1 ,2 ]
Zhang, Zhi [1 ,2 ]
Chen, Junfei [1 ,2 ]
Wang, Jiaxin [1 ,2 ]
Cheng, Xin [1 ,2 ]
Feng, Jiwen [1 ,2 ]
Bao, Qingjia [1 ,2 ]
Liu, Chaoyang [1 ,2 ,3 ]
机构
[1] Chinese Acad Sci, Innovat Acad Precis Measurement Sci & Technol, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance,Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Opt Valley Lab, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Halbach magnet; Low-field NMR; Easy-built; High homogeneity; Optimized; Target field; Passive shimming; Sparse sampling; PERMANENT-MAGNETS; DESIGN; SYSTEM; OIL; SPECTROSCOPY; WATER;
D O I
10.1016/j.jmr.2023.107582
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The aim of this work is to develop a Halbach magnet that possesses characteristics such as easy-built, low cost and high homogeneity for use in a portable low-field NMR (LF-NMR) system. Considering portability, a 4-ring Halbach magnet was designed through simulation and mechanical modelling, which was successfully constructed in a general laboratory setting. The obtained field strength (B0) was 0.169 T, with an initial homogeneity of 8204 ppm within a sphere with a diameter of 20 mm. To enhance robustness, efficiency and effectiveness of shimming, an optimized target-field passive shimming method was proposed. Subsequently, the homemade spectrometer was used to run NMR experiments on the Halbach magnet. The 1H NMR linewidths of water samples became significantly narrower after passive shimming, e.g., the linewidth of a sample with a diameter of 3 mm and a length of 3 mm reduced from 452.3 Hz (62.5 ppm) to 12.9 Hz (1.8 ppm), which was much less than 102 Hz. The NMR results demonstrate that the proposed passive shimming method can achieve high homogeneity, and the developed Halbach magnet is capable of satisfying numerous LF-NMR applications.
引用
收藏
页数:13
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共 45 条
[1]   Deep regression with ensembles enables fast, first-order shimming in low-field NMR [J].
Becker, Moritz ;
Jouda, Mazin ;
Kolchinskaya, Anastasiya ;
Korvink, Jan G. .
JOURNAL OF MAGNETIC RESONANCE, 2022, 336
[2]   Mobile single-sided NMR [J].
Bluemich, B. ;
Perlo, J. ;
Casanova, F. .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2008, 52 (04) :197-269
[3]   Desktop NMR and Its Applications From Materials Science To Organic Chemistry [J].
Bluemich, Bernhard ;
Singh, Kawarpal .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (24) :6996-7010
[4]   NMR at low magnetic fields [J].
Bluemich, Bernhard ;
Casanova, Federico ;
Appelt, Stephan .
CHEMICAL PHYSICS LETTERS, 2009, 477 (4-6) :231-240
[5]   Proposal for a permanent magnet system with a constant gradient mechanically adjustable in direction and strength [J].
Bluemler, Peter .
CONCEPTS IN MAGNETIC RESONANCE PART B-MAGNETIC RESONANCE ENGINEERING, 2016, 46 (01) :41-48
[6]   Accounting for material imperfections in the design and optimization of low cost Halbach magnets [J].
Bogaychuk, A. ;
Kuzmin, V .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2020, 91 (10)
[7]   Recent advances in benchtop NMR spectroscopy and its applications [J].
Castaing-Cordier, Thomas ;
Bouillaud, Dylan ;
Farjon, Jonathan ;
Giraudeau, Patrick .
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 103, 2021, 103 :190-257
[8]   Rapid, accurate, and simultaneous measurement of water and oil contents in the fried starchy system using low-field NMR [J].
Chen, Long ;
Tian, Yaoqi ;
Sun, Binghua ;
Wang, Jinpeng ;
Tong, Qunyi ;
Jin, Zhengyu .
FOOD CHEMISTRY, 2017, 233 :525-529
[9]   Mobile sensor for high resolution NMR spectroscopy and imaging [J].
Danieli, Ernesto ;
Mauler, Joerg ;
Perlo, Juan ;
Bluemich, Bernhard ;
Casanova, Federico .
JOURNAL OF MAGNETIC RESONANCE, 2009, 198 (01) :80-87
[10]   Simultaneous acquisition of multi-nuclei enhanced NMR/MRI by solution-state dynamic nuclear polarization [J].
He, Yugui ;
Zhang, Zhen ;
Feng, Jiwen ;
Huang, Chongyang ;
Chen, Fang ;
Liu, Chaoyang ;
Liu, Maili .
SCIENCE CHINA-CHEMISTRY, 2016, 59 (07) :830-835