Selective oxidation of benzylic alcohols via synergistic bisphosphonium and cobalt catalysis

被引：13

作者：

Ding, Jia ^{[1
,2
]}

Luo, Shuaishuai ^{[1
,2
]}

Xu, Yuanli ^{[3
]}

An, Qing ^{[1
]}

Yang, Yi ^{[3
]}

Zuo, Zhiwei ^{[2
]}

机构：

[1] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[3] Sichuan Univ Sci & Engn, Key Lab Green Chem Sichuan Inst Higher Educ, Innovat Ctr Chenguang High Performance Fluorine Ma, Zigong 643000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 27期

关键词：

EVOLUTION; DEHYDROGENATION;

D O I：

10.1039/d3cc00532a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synergistic photocatalytic system using a bisphosphonium catalyst and a cobalt catalyst has been developed, enabling the selective oxidation of benzylic alcohols under oxidant-free and environmentally benign conditions. High efficiencies have been obtained for a variety of alcohol substrates, and exclusive selectivity for aldehyde products has been achieved across the board. Furthermore, this photocatalytic system proved to be efficient when performed under continuous-flow conditions, even using a simple and easily assembled continuous-flow setup.

引用

页码：4055 / 4058

页数：4

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