Effect of nano-reduced graphene oxide (NRGO) on long-term fracture behavior of Warm Mix Asphalt (WMA)

Recent studies have shown that in addition to ambient temperature, time-dependent factors such as temperature cycles and freeze-thaw cycles (FTCs) affect the speed of creation and growth of low-temperature cracks (LTCs) and intermediate-temperature cracks (ITCs) by creating the aging process in the asphalt mixture. Therefore, it is necessary to study the cracking behavior of asphalt mixtures by considering these factors. In the present study, an attempt was made to evaluate the long-term fracture behavior of Warm Mix Asphalt (WMA) modified with nano-reduced graphene oxide (NRGO) containing vertical and angular cracks under mode I loading conditions at low and intermediate temperatures using Semi-circular bend (SCB) geometry. In order to simulate long-term per-formance, two conditions of 3 FTC and aging process (for 6 days) were applied to the mixtures with and without NRGO, and the results were compared with samples subjected to 0 FTC (short-term performance). The results showed that adding 0.3% and 0.6% NRGO to the WMA mixture increased fracture toughness (KIC), fracture energy (GF), and stiffness under mode I at low and intermediate temperatures. At +15 degrees C and for the geometry containing the vertical crack, the NRGO-modified WMA mixture had better flexibility under 3 FTC than 0 FTC; while, the flexibility of the NRGO-modified WMA mixture decreased under aging process. For geometry con-taining angular crack, flexibility indices improved for NRGO-containing mixtures under 3 FTC and aging process (at +15 degrees C temperature). On the other hand, the results showed that the addition of NRGO to the WMA mixture, while increasing the maximum load at the moment of fracture, caused a decrease in the displacement at the fractured moment at low and intermediate temperatures. This result was obtained for the mixtures that were conditioned under aging process. However, the results showed that applying 3 FTCs decreased the maximum load at the moment of fracture and increased the displacement at the fractured moment. Finally, the results showed that the reduction of fracture indices was higher for WMA and NRGO-modified WMA mixtures under 3 FTCs (at temperatures & PLUSMN;15 degrees C); therefore, applying 3 FTC instead of aging process can be used to evaluate the long-term performance of asphalt mixtures.