Base-mediated one-pot synthesis of alkynylsilanes from terminal alkynes and chlorosilanes

被引：1
|
作者：
Chen, Jianyang [1 ]
Fu, Hongmei [1 ]
He, Huamei [1 ]
Liang, Shuting [1 ]
Luo, Xiaofeng [1 ]
机构：
[1] Chongqing Univ Arts & Sci, Chongqing Key Lab Resource Utilizat Heavy Met Wast, Yongchuan 402160, Peoples R China
来源：
TETRAHEDRON | 2024年 / 152卷
关键词：
One-pot method; Alkynylsilanes; Terminal alkynes; Chlorosilanes; LiN(SiMe3)2; DEHYDROGENATIVE SILYLATION; COUPLING REACTIONS; EFFICIENT; ZINC; 1-ALKYNES; ROUTE; TRIMETHYLSILYLATION; HYDROSILANES; DERIVATIVES; ACTIVATION;
D O I：
10.1016/j.tet.2024.133823
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient one -pot method has been developed to synthesize alkynylsilanes from terminal alkynes by treatment with chlorosilanes and LiN(SiMe3)2. The reaction proceeded smoothly at room temperature, showing a broad substrate scope and good functional group tolerance. The practical application was demonstrated by gram-scale reaction.
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页数：6
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