High-throughput compositional mapping of triple-cation tin-lead perovskites for high-efficiency solar cells

被引：27
作者：
Gunasekaran, Rajendra Kumar [1 ]
Jung, Jina [1 ]
Yang, Sung Woong [1 ]
Yun, Jungchul [1 ]
Yun, Yeonghun [1 ]
Vidyasagar, Devthade [1 ]
Choi, Won Chang [1 ]
Lee, Chang-Lyoul [2 ]
Noh, Jun Hong [3 ]
Kim, Dong Hoe [4 ,5 ]
Lee, Sangwook [1 ,6 ]
机构：
[1] Kyungpook Natl Univ, Sch Mat Sci & Engn, Daegu, South Korea
[2] Adv Photon Res Inst APRI, Gwangju Inst Sci & Technol GIST, Gwangju, South Korea
[3] Korea Univ, Sch Civil Environm & Architectural Engn, Green Sch, Seoul, South Korea
[4] Korea Univ, Dept Mat Sci & Engn, Seoul, South Korea
[5] Korea Univ, Dept Mat Sci & Engn, Seoul 02841, South Korea
[6] Kyungpook Natl Univ, Sch Mat Sci & Engn, Daegu 41566, South Korea
来源：
INFOMAT | 2023年 / 5卷 / 04期
基金：
新加坡国家研究基金会;
关键词：
compositional engineering; mixed tin-lead iodides; narrow-bandgap perovskites; perovskite solar cells; strain relaxation; ternary phase mapping; IODIDE PEROVSKITES; STRAIN RELAXATION; PHASE; METHYLAMMONIUM; STABILITY; OXIDATION; VACANCIES; IMPACT; CESIUM; FILMS;
D O I：
10.1002/inf2.12393
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Mixed tin-lead perovskites suffer from structural instability and rapid tin oxidation; thus, the investigation of their optimal composition ranges is important to address these inherent weaknesses. The critical role of triple cations in mixed Sn-Pb iodides is studied by performing a wide range of compositional screenings over mechanochemically synthesized bulk and solution-processed thin films. A ternary phase map of FA (Sn0.6Pb0.4)I-3, MA(Sn0.6Pb0.4)I-3, and Cs(Sn0.6Pb0.4)I-3 is formed, and a promising composition window of (FA(0.6-x)MA(0.4)Cs(x))Sn0.6Pb0.4I3 (0 <= x <= 0.1) is demonstrated through phase, photoluminescence, and stability evaluations. Solar cell performance and chemical stability across the targeted compositional space are investigated, and FA(0.55)MA(0.4)Cs(0.05)Sn(0.6)Pb(0.4)I(3) with strain-relaxed lattices, reduced defect densities, and improved oxidation stability is demonstrated. The inverted perovskite solar cells with the optimal composition demonstrate a power conversion efficiency of over 22% with an open-circuit voltage of 0.867 V, which corresponds to voltage loss of 0.363 V, promising for the development of narrow-bandgap perovskite solar cells.
引用
收藏
页数：14
相关论文
共 57 条
[1]   Tin(iv) dopant removal through anti-solvent engineering enabling tin based perovskite solar cells with high charge carrier mobilities [J].
Bandara, R. M. I. ;
Jayawardena, K. D. G. I. ;
Adeyemo, S. O. ;
Hinder, S. J. ;
Smith, J. A. ;
Thirimanne, H. M. ;
Wong, N. C. ;
Amin, F. M. ;
Freestone, B. G. ;
Parnell, A. J. ;
Lidzey, D. G. ;
Joyce, H. J. ;
Sporea, R. A. ;
Silva, S. R. P. .
JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (27) :8389-8397
[2]   Progress of Pb-Sn Mixed Perovskites for Photovoltaics: A Review [J].
Bandara, Rajapakshe Mudiyanselage Indrachapa ;
Silva, Shashini M. ;
Underwood, Cameron C. L. ;
Jayawardena, K. D. G. Imalka ;
Sporea, Radu A. ;
Silva, S. Ravi P. .
ENERGY & ENVIRONMENTAL MATERIALS, 2022, 5 (02) :370-400
[3]   Coherent Nanotwins and Dynamic Disorder in Cesium Lead Halide Perovskite Nanocrystals [J].
Bertolotti, Federica ;
Protesescu, Loredana ;
Kovalenko, Maksym V. ;
Yakunin, Sergii ;
Cervellino, Antonio ;
Billinge, Simon J. L. ;
Terban, Maxwell W. ;
Pedersen, Jan Skov ;
Masciocchi, Norberto ;
Guagliardi, Antonietta .
ACS NANO, 2017, 11 (04) :3819-3831
[4]   Mechanochemistry of inorganic and organic systems: what is similar, what is different? [J].
Boldyreva, Elena .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (18) :7719-7738
[5]   Unveiling Roles of Tin Fluoride Additives in High-Efficiency Low-Bandgap Mixed Tin-Lead Perovskite Solar Cells [J].
Chen, Qiyu ;
Luo, Jincheng ;
He, Rui ;
Lai, Huagui ;
Ren, Shengqiang ;
Jiang, Yiting ;
Wan, Zhenxi ;
Wang, Wenwu ;
Hao, Xia ;
Wang, Ye ;
Zhang, Jingquan ;
Constantinou, Iordania ;
Wang, Changlei ;
Wu, Lili ;
Fu, Fan ;
Zhao, Dewei .
ADVANCED ENERGY MATERIALS, 2021, 11 (29)
[6]   Mechanochemical Synthesis of Sn(II) and Sn(IV) Iodide Perovskites and Study of Their Structural, Chemical, Thermal, Optical, and Electrical Properties [J].
El Ajjouri, Yousra ;
Locardi, Federico ;
Gelvez-Rueda, Maria C. ;
Prato, Mirko ;
Sessolo, Michele ;
Ferretti, Maurizio ;
Grozema, Ferdinand C. ;
Palazon, Francisco ;
Bolink, Henk J. .
ENERGY TECHNOLOGY, 2020, 8 (04)
[7]   Efficient Monolithic Perovskite/Perovskite Tandem Solar Cells [J].
Forgacs, David ;
Gil-Escrig, Lidon ;
Perez-Del-Rey, Daniel ;
Momblona, Cristina ;
Werner, Jeremie ;
Niesen, Bjoern ;
Ballif, Christophe ;
Sessolo, Michele ;
Bolink, Henk J. .
ADVANCED ENERGY MATERIALS, 2017, 7 (08)
[8]   Mitigating Open-Circuit Voltage Loss in Pb-Sn Low-Bandgap Perovskite Solar Cells via Additive Engineering [J].
Ghimire, Nabin ;
Bobba, Raja Sekhar ;
Gurung, Ashim ;
Reza, Khan Mamun ;
Laskar, Md Ashiqur Rahman ;
Lamsal, Buddhi Sagar ;
Emshadi, Khalid ;
Pathak, Rajesh ;
Afroz, Mohammad Adil ;
Chowdhury, Ashraful Haider ;
Chen, Ke ;
Bahrami, Behzad ;
Rahman, Sheikh Ifatur ;
Pokharel, Jyotshna ;
Baniya, Abiral ;
Rahman, Md Tawabur ;
Zhou, Yue ;
Qiao, Quinn .
ACS APPLIED ENERGY MATERIALS, 2021, 4 (02) :1731-1742
[9]   Shining Light on the Photoluminescence Properties of Metal Halide Perovskites [J].
Goetz, Katelyn P. ;
Taylor, Alexander D. ;
Paulus, Fabian ;
Vaynzof, Yana .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (23)
[10]   Tin and Mixed Lead-Tin Halide Perovskite Solar Cells: Progress and their Application in Tandem Solar Cells [J].
Gu, Shuai ;
Lin, Renxing ;
Han, Qiaolei ;
Gao, Yuan ;
Tan, Hairen ;
Zhu, Jia .
ADVANCED MATERIALS, 2020, 32 (27)
123456