Synthesis and characterization of zinc(II) phthalocyanine containing 17-membered macrocyclic moiety as new extractant for the removal of Ag(I) from aqueous solution

被引：0

作者：

Yildiz, Yasemin Baygu ^{[1
]}

机构：

[1] Pamukkale Univ, Tavas Vocat High Sch, Denizli, Turkiye

来源：

TRANSITION METAL CHEMISTRY | 2024年 / 49卷 / 04期

关键词：

CROWN-ETHERS; METAL-IONS; COMPLEXATION; COORDINATION; CATALYSTS; LIGAND; CU(II); WATER;

D O I：

10.1007/s11243-024-00577-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new aza-thia macrocycle compound was obtained with high dilution reaction. A new zinc(II) phthalocyanine containing four 17-membered macrocycle moieties with nitrogen-sulfur donor atoms was synthesized in a multi-step reaction sequence. Zn(II) phthalocyanine (S4N-ZnPc) and all of the new compounds were characterized by elemental analysis and different spectroscopic methods such as 1H NMR, 13C NMR, IR, UV-vis and mass. Obtained macrocyclic compounds 6 and S4N-ZnPc were used in solvent extraction of metals such as Ag+, Hg2+, Cd2+, Zn2+, Cu2+, Ni2+, Pb2+ and Cr3+ from aqueous phase to the organic phase. The results of two-phase extraction studies on new macrocyclic compounds showed very high selectivity for silver ions compared to other metal cations.

引用

页码：237 / 244

页数：8

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