Synthesis, Growth and Characterization of L-Glycine Glycinium Hydrochloride Monohydrate Crystals: A New Nonlinear Optical Material

被引:0
|
作者
Sudhakar, C. [1 ,2 ]
Jothi, L. [3 ]
机构
[1] Salem Sowdeswari Coll, Dept Phys, Salem 636010, Tamil Nadu, India
[2] Periyar Univ, Res & Dev Cell, Salem 636011, India
[3] Namakkal Kavignar Ramalingam Govt Arts Coll Women, Res Dept Phys, Namakkal 637001, Tamil Nadu, India
关键词
Semi-organic crystals; slow evaporation; single crystal XRD; Raman spectrum; TGA; SHG; SINGLE-CRYSTALS; ACID; PURE; DYNAMICS;
D O I
10.1142/S2251237324400057
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
L-Glycine Glycinium Hydrochloride Monohydrate (L-GGHCM), a new second-order nonlinear optical crystal, was produced using the slow evaporation process with double distilled water as a solvent. Powder XRD analysis was completed in order to identify the crystallinity sample. In the orthorhombic system with space group P212121, L-GGHCM expands in accordance with structural improvement. A single crystal XRD analysis discovered the extended framework architecture of L-GGHCM, a self-assembly process involving short-range and directed bonds, among many other interactions. The optical quality and transmission of the synthesized crystal were determined using UV-visible and fluorescence spectrum analysis. The effectiveness of L-GGHCM's second harmonic generation is roughly 1.7 times compared to a standard potassium dihydrogen orthophosphate sample. Thermal analysis is used to study a material's thermal stability and internal decomposition. L-glycine glycinium hydrochloride monohydrate crystal is shown to have good thermal stability.
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页数:9
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