Cu4I4-cubane cluster based on tris(p-anisyl)arsine: synthesis, crystal structure and photophysical properties

被引：4

作者：

Demyanov, Yan V. ^{[1
]}

Rakhmanova, Marianna I. ^{[1
]}

Bagryanskaya, Irina Yu. ^{[2
]}

Artemev, Alexander V. ^{[1
]}

机构：

[1] Russian Acad Sci, A V Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Russian Acad Sci, N N Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 04期

关键词：

copper(i) complexes; tris(p-anisyl)arsine; cubane-like clusters; photoluminescence; crystal structure; COPPER IODIDE CLUSTERS; CU(I); COMPLEXES;

D O I：

10.1016/j.mencom.2023.06.014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new cubane cluster [Cu4I4(AsAn3)4] was synthesized in 82% yield by the reaction of tris(p-anisyl)arsine (AsAn3) with CuI. At ambient temperature, this cluster exhibits bright yellow-green phosphorescence (& ANGS;max = 546 nm) with the quantum yield of 35% and 4.1 ms decay time.

引用

页码：484 / 486

页数：3

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