Mimicking Natural Antioxidant Systems for Improved Photostability in Wide-Band-Gap Perovskite Solar Cells

被引：17

作者：

Bisconti, Francesco ^{[1
]}

Leoncini, Mauro ^{[1
,2
]}

Gambino, Salvatore ^{[1
]}

Vanni, Nadir ^{[1
,2
]}

Carallo, Sonia ^{[1
]}

Russo, Francesca ^{[3
,4
]}

Armenise, Vincenza ^{[3
]}

Listorti, Andrea ^{[3
]}

Colella, Silvia ^{[5
]}

Valastro, Salvatore ^{[6
]}

Alberti, Alessandra ^{[6
]}

Mannino, Giovanni ^{[6
]}

Rizzo, Aurora ^{[1
]}

机构：

[1] CNR NANOTEC Ist Nanotecnol, I-73100 Lecce, Italy

[2] Univ Salento, Dipartimento Matemat & Fis E De Giorgi, I-73100 Lecce, Italy

[3] Univ Bari, Dipartimento Chim, I-70126 Bari, Italy

[4] Politecn Bari, Dipartimento Ingn Elettr & Informaz, I-70126 Bari, Italy

[5] Univ Bari, CNR NANOTEC, Dipartimento Chim, I-70126 Bari, Italy

[6] CNR IMM, I-95121 Catania, Italy

来源：

ACS NANO | 2023年 / 18卷 / 02期

关键词：

perovskite; stability; beta-carotene; bioinspired; PSC; solar cells; STABILITY; EFFICIENT; PERFORMANCE; CAROTENOIDS; DEGRADATION; INTERFACE; PROSPECTS;

D O I：

10.1021/acsnano.3c09437

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fostered by the top power conversion efficiencies (PCEs) of lab-scale devices, industrialization of perovskite solar cells is underway. Nevertheless, the intrinsically poor stability of these materials still represents a major concern. Herein, inspired by Nature, the use of beta-carotene in perovskite solar cells is proposed to mimic its role as a protective pigment, as occurs in natural photosynthesis. Laser-mediated photostability (LMPS) assessment, Fourier-transform infrared spectra analysis acquired in attenuate total reflectance (ATR-FTIR), spectroscopy ellipsometry (SE), and time-resolved photoluminescence (TRPL) measurements under stress conditions prove that the inclusion of a thin beta-carotene interlayer promotes a high improvement in the photostability of the perovskite films against photooxidation. Importantly, this is accompanied by an improvement of the solar cell PCE that approaches 20% efficiency with no hysteresis, which is among the highest values reported for a mixed halide (I-Br) perovskite with a band gap of 1.74 eV, relevant for coupling with silicon in tandem cells.

引用

页码：1573 / 1581

页数：9

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