Influence of Fluorinated Substituents on the Near-Infrared Phosphorescence of 5d Metallocorroles

被引：3

作者：

Johannessen, Krister Engedal ^{[1
]}

Johansen, Martin Amund Langaas ^{[1
]}

Einrem, Rune F. ^{[1
]}

McPherson, Laura J. McCormick J. ^{[2
]}

Alemayehu, Abraham B. ^{[1
]}

Borisov, Sergey M. ^{[3
]}

Ghosh, Abhik ^{[1
]}

机构：

[1] UiT Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway

[2] Univ Southampton, Sch Chem, EPSRC Natl Crystallog Serv, Southampton SO17 1BJ, England

[3] Graz Univ Technol, Inst Analyt Chem & Food Chem, A-8010 Graz, Austria

来源：

ACS ORGANIC & INORGANIC AU | 2023年 / 3卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

Fluorinated compounds; fluorous; corrole; phosphorescence; triplet photosensitizer; gold; rhenium; MOLECULAR-STRUCTURE; IR PHOSPHORESCENCE; GOLD CORROLES; RHENIUM-OXO; COMPLEXES; OXYGEN; INSIGHTS;

D O I：

10.1021/acsorginorgau.3c00016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of fluorinated substituents on the luminescentpropertiesof rhenium-oxo, osmium-nitrido, and gold triarylcorroles was studiedvia a comparison of four ligands: triphenylcorrole (TPC), tris(p-trifluoromethylphenyl)corrole (TpCF(3)PC), tris{3,5-bis(trifluoromethyl)phenyl}corrole (T3,5-CF3PC), and tris(pentafluorophenyl)corrole (TPFPC). For eachmetal series examined, fluorinated substituents were found to enhancethe luminescent properties, with the phosphorescence quantum yieldsand triplet decay times increasing in the order TPC < TpCF(3)PC < T3,5-CF3PC < TPFPC.Among the 11 complexes examined, the highest phosphorescence quantumyield, 2.2%, was recorded for Re[TPFPC](O).

引用

页码：241 / 245

页数：5

共 37 条

[1] The Story of 5d Metallocorroles: From Metal-Ligand Misfits to New Building Blocks for Cancer Phototherapeutics
Alemayehu, Abraham B.
Thomas, Kolle E.
Einrem, Rune F.
Ghosh, Abhik
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2021, 54 (15) : 3095 - 3107
[2] Synthesis and molecular structure of perhalogenated rhenium-oxo corroles
Alemayehu, Abraham B.
Einrem, Rune F.
McCormick-McPherson, Laura J.
Settineri, Nicholas S.
Ghosh, Abhik
[J]. SCIENTIFIC REPORTS, 2020, 10 (01)
[3] Rhenium-imido Corroles
Alemayehu, Abraham B.
Teat, Simon J.
Borisov, Sergey M.
Ghosh, Abhik
[J]. INORGANIC CHEMISTRY, 2020, 59 (09) : 6382 - 6389
[4] Stable Platinum(IV) Corroles: Synthesis, Molecular Structure, and Room-Temperature Near-IR Phosphorescence
Alemayehu, Abraham B.
McCormick, Laura J.
Gagnon, Kevin J.
Borisov, Sergey M.
Ghosh, Abhik
[J]. ACS OMEGA, 2018, 3 (08): : 9360 - 9368
[5] Gold Tris(carboxyphenyl)corroles as Multifunctional Materials: Room Temperature Near-IR Phosphorescence and Applications to Photodynamic Therapy and Dye-Sensitized Solar Cells
Alemayehu, Abraham B.
Day, Nicholas U.
Mani, Tomoyasu
Rudine, Alexander B.
Thomas, Kolle E.
Gederaas, Odrun A.
Vinogradov, Sergei A.
Wamser, Carl C.
Ghosh, Abhik
[J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (29) : 18935 - 18942
[6] Oxidative Metalation as a Route to Size-Mismatched Macrocyclic Complexes: Osmium Corroles
Alemayehu, Abraham B.
Gagnon, Kevin J.
Terner, James
Ghosh, Abhik
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (52) : 14411 - 14414
[7] Platinum corroles
Alemayehu, Abraham B.
Vazquez-Lima, Hugo
Beavers, Christine M.
Gagnon, Kevin J.
Bendix, Jesper
Ghosh, Abhik
[J]. CHEMICAL COMMUNICATIONS, 2014, 50 (76) : 11093 - 11096
[8] Gold corroles
Alemayehu, Abraham B.
Ghosh, Abhik
[J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2011, 15 (02) : 106 - 110
[9] PREPARATION OF FUNCTIONALIZED POLYHALOGENATED TETRAARYL-PORPHYRINS BY SELECTIVE SUBSTITUTION OF THE PARA-FLUORINES OF MESO-TETRA-(PENTAFLUOROPHENYL)PORPHYRINS
BATTIONI, P
BRIGAUD, O
DESVAUX, H
MANSUY, D
TRAYLOR, TG
[J]. TETRAHEDRON LETTERS, 1991, 32 (25) : 2893 - 2896
[10] Ambient-temperature near-IR phosphorescence and potential applications of rhenium-oxo corroles
Borisov, Sergey M.
Einrem, Rune F.
Alemayehu, Abraham B.
Ghosh, Abhik
[J]. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2019, 18 (05) : 1166 - 1170

← 1 2 3 4 →