Crystal structure and Hirshfeld surface analysis of bis(μ-4-tert-butoxy-4-oxobut-2-en-2-olato)bis[(4-tert-butoxy-4-oxobut-2-en-2-olato)ethanolzinc(II)]

被引：0
|
作者：
Shtokvysh, Olherd O. [1 ]
Dyakonenko, Viktoriya V. [1 ,2 ]
Koval, Lyudmila I. [1 ]
Pekhnyo, Vasyl I. [1 ]
机构：
[1] Natl Acad Sci Ukraine, VI Vernadskii Inst Gen & Inorgan Chem, Akad Palladin Ave 32-34, UA-03142 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, SSI Inst Single Crystals, Nauki Ave 60, UA-61001 Kharkiv, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; complex; zinc; tertbutyl acetoacetate; keto ester; ethanol; binuclear structure; COMPLEXES; PRECURSORS; PROGRAM;
D O I：
10.1107/S2056989023003377
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecular and crystal structure of the title binuclear Zn2+ complex, [Zn-2(C8H13O3)4(C2H5OH)(2)], with enolated anionic tert-butylacetoacetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octahedra formed by six oxygen atoms that belong to three ligand molecules and a coordinated ethanol molecule. In the crystal phase, alternating layers can be distinguished parallel to the ac plane. A Hirshfeld surface analysis showed that there are no strong intermolecular interactions in the structure. The most significant contributions to the overall crystal packing are from H center dot center dot center dot H intermolecular contacts.
引用
收藏
页码：478 / +
页数：10
相关论文
共 50 条
  • [21] Crystal structure and Hirshfeld surface analysis of (2E,2′E)-1,1′-[selenobis(4,1 -phenylene)]bis[3-(4-chlorophenyl)prop-2-en-1 -one]
    Bouraoui, Hazem
    Mechehoud, Youcef
    Chetioui, Souheyla
    Touzani, Rachid
    Medjani, Meriem
    Benmilat, Ahmed
    Boudjada, Ali
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1724 - +
  • [22] Crystal structure of (2-{3-[4-(4'-cyanobiphenyl-4-yloxy)butoxy]pyridin-2-yl-kappa N}-5-(dodecyloxy)phenyl-kappa C-1)(9-oxo-tetracos-7-en-7-olato-kappa O-2,O ')-platinum(II)
    Luo, Kaijun
    Liu, Hanlin
    Guo, Qing
    Luo, Daibing
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M392 - +
  • [23] Bis[2-(4,5-diohenyl-1H-imidazol-2-yl)-4-nitro-phenolato]copper(II) dihydrate: crystal structure and Hirshfeld surface analysis
    Chettri, Sailesh
    Brahman, Dhiraj
    Sinha, Biswajit
    Jotani, Mukesh M.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1664 - +
  • [24] Crystal and Molecular Structure of 2, 5-bis(butoxy) 1,4-bis (biphength ethynyl) benzene and 2, 5-bis (Octyloxy) 1, 4-bis (biphenyl ethynyl) benzene
    Chawdhury, S. A.
    Raithby, Paul R.
    Younus, Muhammad
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2005, 61 : C497 - C497
  • [25] 2,2':4,4,":4',4'''-Quaterpyridine: synthesis, crystalstructure description, and Hirshfeld surface analysis
    Aderinto, Stephen O.
    Thomas, Jim A.
    Robertson, Craig C.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 356 - +
  • [26] Bis{N′-[3-(4-nitrophenyl)-1-phenylprop-2-en-1-ylidene]-N-phenylcarbamimidothioato}zinc(II): crystal structure, Hirshfeld surface analysis and computational study
    Tan, Ming Yueh
    Kwong, Huey Chong
    Crouse, Karen A.
    Ravoof, Thahira B. S. A.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 839 - +
  • [27] Synthesis and Structural Characterization of Bis[(cyclohexylamino)pent-2-en-4-onato]-Chromium(II)
    Monillas, Wesley H.
    Yap, Glenn P. A.
    Theopold, Klaus H.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (05) : 380 - 383
  • [28] Crystal structure, Hirshfeld surface analysis and interaction energy and DFT studies of 4-[(prop-2-en-1-yloxy)methyl]-3,6-bis(pyridin-2-yl)pyridazine
    Filali, Mouad
    Sebbar, Nada Kheira
    Hokelek, Tuncer
    Mague, Joel T.
    Chakroune, Said
    Ben-Tama, Abdessalam
    El Hadrami, El Mestafa
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1321 - +
  • [29] Crystal structure and Hirshfeld analysis of di-tert-butyl 2,2′-[(ethylazanediyl)bis(methylene)]bis(1H-pyrrole-1-carboxylate)
    Kvyatkovskaya, Elizaveta A.
    Atioglu, Zeliha
    Akkurt, Mehmet
    Epifanova, Polina P.
    Valchuk, Karina S.
    Khrustalev, Victor N.
    Bhattarai, Ajaya
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 1827 - +
  • [30] Crystal structure and the magnetic properties of tris(2-chloromethyl-4-oxo-4H-pyran-5-olato-κ2O5,O4)iron(III)
    Hryniewicz, K.
    Stadnicka, K.
    Adamski, A.
    Pattek-Janczyk, A.
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (06) : 977 - 987
12345