Interfacial Assembly of 2D Graphene-Derived Ion Channels for Water-Based Green Energy Conversion

The utilization of sustained and green energy is believed to alleviate increasing menace of global environmental concerns and energy dilemma. Interfacial assembly of 2D graphene-derived ion channels (2D-GDICs) with tunable ion/fluid transport behavior enables efficient harvesting of renewable green energy from ubiquitous water, especially for osmotic energy harvesting. In this review, various interfacial assembly strategies for fabricating diverse 2D-GDICs are summarized and their ion transport properties are discussed. This review analyzes how particular structure and charge density/distribution of 2D-GDIC can be modulated to minimize internal resistance of ion/fluid transport and enhance energy conversion efficiency, and highlights stimuli-responsive functions and stability of 2D-GDIC and further examines the possibility of integrating 2D-GDIC with other energy conversion systems. Notably, the presented preparation and applications of 2D-GDIC also inspire and guide other 2D materials to fabricate sophisticated ion channels for targeted applications. Finally, potential challenges in this field is analyzed and a prospect to future developments toward high-performance or large-scale real-word applications is offered. Rational materials selection/design and thorough mechanism research in water-based green energy conversion are essential scientific issues to be imminently discussed for future development of 2D graphene-derived ion channels (2D-GDICs) through interfacial assembly. Such review and prospects about 2D-GDIC from synthesis to applications including stability and functionalization would also provide a reference for other 2D materials to fabricate sophisticated ion channels.image