Ultrahigh-Temperature Mafic Granulites in the Rauer Group, East Antarctica: Evidence from Conventional Thermobarometry, Phase Equilibria Modeling, and Rare Earth Element Thermometry

The Rauer Group in East Antarctica is a typical high- to ultrahigh-temperature (HT-UHT) granulite-facies terrane. As UHT metamorphism has been recognized only in Mg-Al-rich pelitic granulites from the Mather Paragneiss, the regional extent of UHT metamorphism remains uncertain, which has hindered our understanding of the genesis and tectonic setting of UHT metamorphism in the Rauer Group. In this study, representative samples of mafic granulite were selected from Archean crustal domains to constrain the peak metamorphic conditions and P-T path and to assess the regional extent of UHT metamorphism in the Rauer Group. Integrated results from mineral reaction histories, thermobarometry, and phase equilibria modeling indicate a multi-stage clockwise P-T evolution for mafic granulites involving pre-peak compression, heating to UHT peak conditions, post-peak near-isothermal decompression under UHT conditions, and subsequent decompressional cooling. The pre-peak prograde history is based mainly on the inclusion assemblage of clinopyroxene + plagioclase + amphibole + quartz + ilmenite +/- orthopyroxene +/- k-feldspar within porphyroblastic garnet and clinopyroxene and records the transformation from a quartz-present to quartz-absent system. The UHT peak conditions are well constrained at 930 degrees C-1030 degrees C and 10.6-12.8 kbar on the basis of the stability field of the observed peak assemblage of (orthopyroxene-quartz)-free garnet + clinopyroxene + plagioclase + amphibole + ilmenite + melt, as well as measured mineral compositions, including the high Ti content in amphibole (Ti = 0.38-0.42 p.f.u.), the anorthite content of coarse-grained plagioclase cores (X-An = 0.35-0.42), and the grossular content in garnet (X-Grs = similar to 0.21) in P-T pseudosections. The peak T conditions are consistent with thermometric estimates in the range of 930 degrees C-1030 degrees C obtained from garnet-clinopyroxene, garnet-orthopyroxene, and Ti-in-amphibole thermometers, and are slightly lower than estimates (1020 degrees C-1120 degrees C) obtained from thermometers based on rare earth elements. The near-isothermal decompression under UHT conditions can be divided into two stages. The early stage is recorded by coronae of orthopyroxene + plagioclase around clinopyroxene and core-mantle/rim anorthite-increasing zoning in plagioclase. The late stage is identified from symplectites of orthopyroxene + plagioclase +/- amphibole around porphyroblastic garnet, which were formed at the expense of garnet at 915 degrees C-950 degrees C and 7.6-8.2 kbar as inferred from the amphibole-plagioclase thermometer. The subsequent decompressional cooling to fluid-absent solidus conditions (similar to 875 degrees C and similar to 6.5 kbar) is indicated by the growth of biotite, which formed at the expense of symplectic minerals, reflecting back-reaction of melt with symplectite minerals. The peak UHT metamorphic conditions and clockwise P-T path of the studied mafic granulites from the Archean crustal domains are similar to those of Mg-Al-rich pelitic UHT granulites from the Mather Paragneiss. The UHT conditions recorded by the mafic granulites, combined with previously identified isolated UHT localities in the Rauer Group, imply that UHT metamorphism in the Rauer Group occurred over a much wider region than previously thought and probably extends over the whole Archean crustal domain. Our findings have general significance in understanding the regional extent of other UHT granulite-facies terranes worldwide.