A three-dimensional Mn-based MOF as a high-performance supercapacitor electrode

被引：49
作者：
Rong, Hongren [1 ,2 ]
Song, Peng [1 ,2 ]
Gao, Gexiang [1 ,2 ]
Jiang, Qingyan [1 ,2 ]
Chen, Xiaojuan [1 ,2 ]
Su, LiXin [1 ,2 ]
Liu, Wen-Long [3 ]
Liu, Qi [1 ,2 ]
机构：
[1] Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
[2] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Jiangsu, Peoples R China
[3] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225009, Jiangsu, Peoples R China
来源：
DALTON TRANSACTIONS | 2023年 / 52卷 / 07期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; ELECTROCHEMICAL ENERGY-STORAGE; COORDINATION POLYMER SYNTHESIS; ROBUST; DESIGN;
D O I：
10.1039/d2dt02857c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Developing new high-performance electrode materials for improving the energy density of supercapacitors is an important task. Herein, a new three-dimensional (3D) metal-orgainc framework (MOF) [Mn(BGPD)(H2O)(2)] (Mn-BGPD; BGPD = N,N '-bis(glycinyl)pyromellitic diimide) was synthesized. When Mn-BGPD is used as the electrode material of supercapacitors, in a three-electrode setup, it shows an outstanding specific capacitance of 832.6 F g(-1) at a current density of 1 A g(-1). The asymmetrical supercapacitor of Mn-BGPD shows an attractive specific capacitance of 100 F g(-1) at 1 A g(-1), which corresponds to an excellent energy density of 35.5 W h kg(-1). Moreover, better cycling stability with a capacitance retention of 46.7% is also shown. The high electrochemical performance makes Mn-BGPD a very promising electrode material for supercapacitors.
引用
收藏
页码：1962 / 1969
页数：8
相关论文
共 63 条
  • [1] Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes
    Bi, Sheng
    Banda, Harish
    Chen, Ming
    Niu, Liang
    Chen, Mingyu
    Wu, Taizheng
    Wang, Jiasheng
    Wang, Runxi
    Feng, Jiamao
    Chen, Tianyang
    Dinca, Mircea
    Kornyshev, Alexei A.
    Feng, Guang
    [J]. NATURE MATERIALS, 2020, 19 (05) : 552 - +
  • [2] A Hybrid Supercapacitor based on Porous Carbon and the Metal-Organic Framework MIL-100(Fe)
    Campagnol, Nicolo
    Romero-Vara, Ricardo
    Deleu, Willem
    Stappers, Linda
    Binnemans, Koen
    De Vos, Dirk E.
    Fransaer, Jan
    [J]. CHEMELECTROCHEM, 2014, 1 (07): : 1182 - 1188
  • [3] Enhanced electrochemical performance of MnO2 nanoparticles: graphene aerogels as conductive substrates and capacitance contributors
    Chen, Huaxia
    Lu, Xingyu
    Zhang, Lili
    Sui, Dianpeng
    Wang, Chao
    Meng, Fanbao
    Qi, Wei
    [J]. DALTON TRANSACTIONS, 2021, 50 (25) : 8776 - 8784
  • [4] Synthesis and structural diversity of d10 metal coordination polymers constructed from new semi-rigid bis(3-methyl-1H-pyrazole-4-carboxylic acid) alkane ligands
    Cheng, Meiling
    Wang, Qinghua
    Bao, Jinting
    Wu, Yujuan
    Sun, Lin
    Yang, Bingxin
    Liu, Qi
    [J]. NEW JOURNAL OF CHEMISTRY, 2017, 41 (12) : 5151 - 5160
  • [5] 3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities
    Choi, Bong Gill
    Yang, MinHo
    Hong, Won Hi
    Choi, Jang Wook
    Huh, Yun Suk
    [J]. ACS NANO, 2012, 6 (05) : 4020 - 4028
  • [6] Supercapacitors of Nanocrystalline Metal-Organic Frameworks
    Choi, Kyung Min
    Jeong, Hyung Mo
    Park, Jung Hyo
    Zhang, Yue-Biao
    Kang, Jeung Ku
    Yaghi, Omar M.
    [J]. ACS NANO, 2014, 8 (07) : 7451 - 7457
  • [7] Two-dimensional layered nickel-based coordination polymer for supercapacitive performance
    Deka, Rakesh
    Kumar, Viresh
    Rajak, Richa
    Mobin, Shaikh M.
    [J]. SUSTAINABLE ENERGY & FUELS, 2022, 6 (12): : 3014 - 3024
  • [8] Vertically co-oriented two dimensional metal-organic frameworks for packaging enhanced supercapacitive performance
    Deng, Ting
    Zhang, Wei
    Arcelus, Oier
    Wang, Dong
    Shi, Xiaoyuan
    Zhang, Xiaoyu
    Carrasco, Javier
    Rojo, Teofilo
    Zheng, Weitao
    [J]. COMMUNICATIONS CHEMISTRY, 2018, 1
  • [9] Co8-MOF-5 as electrode for supercapacitors
    Diaz, Rauel
    Gisela Orcajo, M.
    Botas, Juan A.
    Calleja, Guillermo
    Palma, Jesus
    [J]. MATERIALS LETTERS, 2012, 68 : 126 - 128
  • [10] Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance
    Feng, Dawei
    Lei, Ting
    Lukatskaya, Maria R.
    Park, Jihye
    Huang, Zhehao
    Lee, Minah
    Shaw, Leo
    Chen, Shucheng
    Yakovenko, Andrey A.
    Kulkarni, Ambarish
    Xiao, Jianping
    Fredrickson, Kurt
    Tok, Jeffrey B.
    Zou, Xiaodong
    Cui, Yi
    Bao, Zhenan
    [J]. NATURE ENERGY, 2018, 3 (01): : 30 - 36
1234567