Biobased 2,5-Bis(hydroxymethyl)furan as a Versatile Building Block for Sustainable Polymeric Materials

被引：45
作者：
Post, Cornelis [1 ,2 ]
Maniar, Dina [1 ]
Voet, Vincent S. D. [2 ]
Folkersma, Rudy [2 ]
Loos, Katja [1 ]
机构：
[1] Univ Groningen, Macromol Chem & New Polymer Mat, NL-9747 AG Groningen, Netherlands
[2] NHL Stenden Univ Appl Sci, Circular Plast, NL-7811 KL Emmen, Netherlands
来源：
ACS OMEGA | 2023年 / 8卷 / 10期
关键词：
FURAN-DERIVATIVES; TEREPHTHALIC ACID; NEW-GENERATION; COPOLYESTERS; POLYESTERS; BIOMASS; CONVERSION; SUCCINATE); BIODEGRADABILITY; DEGRADABILITY;
D O I：
10.1021/acsomega.2c07629
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Furanic polymers, currently mainly represented by polyethylene 2,5-furandicarboxylate (PEF), also known as poly-ethylene furanoate, have a fantastic potential to replace fossil-based polymers: for example, polyethylene terephthalate (PET). While 2,5-furandicarboxylic acid (FDCA), a precursor of PEF, and its derived polymers have been studied extensively, 2,5-bis-(hydroxymethyl)furan (BHMF) has received relatively little attention so far. Similarly to FDCA, BHMF is a biobased platform chemical derived from renewable sources such as sugars. This review highlights different polymerization techniques for BHMF-based polyesters and addresses BHMF's relative instability during the synthesis of BHMF-derived polymers, including polycarbonates and polyurethanes. Furthermore, the degradability of furanic polyesters is discussed and BHMF's toxicity is briefly elaborated.
引用
收藏
页码：8991 / 9003
页数：13
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