Biobased 2,5-Bis(hydroxymethyl)furan as a Versatile Building Block for Sustainable Polymeric Materials

被引：44
作者：
Post, Cornelis [1 ,2 ]
Maniar, Dina [1 ]
Voet, Vincent S. D. [2 ]
Folkersma, Rudy [2 ]
Loos, Katja [1 ]
机构：
[1] Univ Groningen, Macromol Chem & New Polymer Mat, NL-9747 AG Groningen, Netherlands
[2] NHL Stenden Univ Appl Sci, Circular Plast, NL-7811 KL Emmen, Netherlands
来源：
ACS OMEGA | 2023年 / 8卷 / 10期
关键词：
FURAN-DERIVATIVES; TEREPHTHALIC ACID; NEW-GENERATION; COPOLYESTERS; POLYESTERS; BIOMASS; CONVERSION; SUCCINATE); BIODEGRADABILITY; DEGRADABILITY;
D O I：
10.1021/acsomega.2c07629
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Furanic polymers, currently mainly represented by polyethylene 2,5-furandicarboxylate (PEF), also known as poly-ethylene furanoate, have a fantastic potential to replace fossil-based polymers: for example, polyethylene terephthalate (PET). While 2,5-furandicarboxylic acid (FDCA), a precursor of PEF, and its derived polymers have been studied extensively, 2,5-bis-(hydroxymethyl)furan (BHMF) has received relatively little attention so far. Similarly to FDCA, BHMF is a biobased platform chemical derived from renewable sources such as sugars. This review highlights different polymerization techniques for BHMF-based polyesters and addresses BHMF's relative instability during the synthesis of BHMF-derived polymers, including polycarbonates and polyurethanes. Furthermore, the degradability of furanic polyesters is discussed and BHMF's toxicity is briefly elaborated.
引用
收藏
页码：8991 / 9003
页数：13
相关论文
共 50 条
[41]   Selective Hydrogenation of 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan over a Cheap Carbon-Nanosheets-Supported Zr/Ca Bimetallic Catalyst [J].
Zhang, Junhua ;
Qi, Zhaohua ;
Liu, Yao ;
Wei, Junnan ;
Tang, Xing ;
He, Liang ;
Peng, Lincai .
ENERGY & FUELS, 2020, 34 (07) :8432-8439
[42]   Cu-Co nanoparticles supported on nitrogen-doped carbon: An efficient catalyst for hydrogenation of 5-hydroxymethylfurfural into 2,5-bis (hydroxymethyl)furan [J].
Zhao, Wenguang ;
Zhu, Xiaoting ;
Zeng, Zhijuan ;
Lei, Jing ;
Huang, Zexing ;
Xu, Qiong ;
Liu, Xianxiang ;
Yang, Yongjun .
MOLECULAR CATALYSIS, 2022, 524
[43]   One-pot synthesis of 2,5-bis(hydroxymethyl)furan from biomass derived 5-(chloromethyl)furfural in high yield [J].
Chen, Binglin ;
Feng, Yunchao ;
Ma, Sen ;
Xie, Weizhen ;
Yan, Guihua ;
Li, Zheng ;
Sperry, Jonathan ;
Yang, Shuliang ;
Tang, Xing ;
Sun, Yong ;
Lin, Lu ;
Zeng, Xianhai .
JOURNAL OF ENERGY CHEMISTRY, 2023, 76 :421-428
[44]   Improved synthesis of 2,5-bis(hydroxymethyl)furan from 5-hydroxymethylfurfural using acclimatized whole cells entrapped in calcium alginate [J].
Xu, Zhong-Hua ;
Cheng, Ai-Di ;
Xing, Xu-Pu ;
Zong, Min-Hua ;
Bai, Yun-Peng ;
Li, Ning .
BIORESOURCE TECHNOLOGY, 2018, 262 :177-183
[45]   An efficient approach to synthesizing 2,5-bis(N-methyl-aminomethyl)furan from 5-hydroxymethylfurfural via 2,5-bis(N-methyl-iminomethyl)furan using a two-step reaction in one pot [J].
Zhang, Jie ;
Jia, Wenlong ;
Sun, Yong ;
Yang, Shuliang ;
Tang, Xing ;
Zeng, Xianhai ;
Lin, Lu .
GREEN CHEMISTRY, 2021, 23 (15) :5656-5664
[46]   Enzymatic synthesis of biobased aliphatic-aromatic oligoesters using 5,5′-bis(hydroxymethyl)furoin as a building block [J].
Baraldi, Serena ;
Fantin, Giancarlo ;
Di Carmine, Graziano ;
Ragno, Daniele ;
Brandolese, Arianna ;
Massi, Alessandro ;
Bortolini, Olga ;
Marchetti, Nicola ;
Giovannini, Pier Paolo .
RSC ADVANCES, 2019, 9 (50) :29044-29050
[47]   Efficient reduction of 5-hydroxymethylfurfural to 2, 5-bis (hydroxymethyl) furan by a fungal whole-cell biocatalyst [J].
Chen, Dong ;
Cang, Ran ;
Zhang, Zhi-Dong ;
Huang, He ;
Zhang, Zhi-Gang ;
Ji, Xiao-Jun .
MOLECULAR CATALYSIS, 2021, 500
[48]   Carbonate-Catalyzed Room-Temperature Selective Reduction of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan [J].
Long, Jingxuan ;
Zhao, Wenfeng ;
Xu, Yufei ;
Li, Hu ;
Yang, Song .
CATALYSTS, 2018, 8 (12)
[49]   Catalytic transfer hydrogenation of biomass-derived 5-hydroxymethyl furfural to the building block 2,5-bishydroxymethyl furan [J].
Hao, Weiwei ;
Li, Weifeng ;
Tang, Xing ;
Zeng, Xianhai ;
Sun, Yong ;
Liu, Shijie ;
Lin, Lu .
GREEN CHEMISTRY, 2016, 18 (04) :1080-1088
[50]   Insight into the mechanism of 5-hydroxymethylfurfural electroreduction to 2,5-bis(hydroxymethyl)furan over Cu anchored N-doped carbon nanosheets [J].
Wu, Haoran ;
Chen, Xinwei ;
Xu, Haishan ;
Yang, Runlu ;
Wang, Xin ;
Chen, Junying ;
Xie, Zhenbing ;
Wu, Liang ;
Mai, Yiyong .
NANO RESEARCH, 2024, 17 (09) :7991-7999
12345