Biobased 2,5-Bis(hydroxymethyl)furan as a Versatile Building Block for Sustainable Polymeric Materials

被引：44
作者：
Post, Cornelis [1 ,2 ]
Maniar, Dina [1 ]
Voet, Vincent S. D. [2 ]
Folkersma, Rudy [2 ]
Loos, Katja [1 ]
机构：
[1] Univ Groningen, Macromol Chem & New Polymer Mat, NL-9747 AG Groningen, Netherlands
[2] NHL Stenden Univ Appl Sci, Circular Plast, NL-7811 KL Emmen, Netherlands
来源：
ACS OMEGA | 2023年 / 8卷 / 10期
关键词：
FURAN-DERIVATIVES; TEREPHTHALIC ACID; NEW-GENERATION; COPOLYESTERS; POLYESTERS; BIOMASS; CONVERSION; SUCCINATE); BIODEGRADABILITY; DEGRADABILITY;
D O I：
10.1021/acsomega.2c07629
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Furanic polymers, currently mainly represented by polyethylene 2,5-furandicarboxylate (PEF), also known as poly-ethylene furanoate, have a fantastic potential to replace fossil-based polymers: for example, polyethylene terephthalate (PET). While 2,5-furandicarboxylic acid (FDCA), a precursor of PEF, and its derived polymers have been studied extensively, 2,5-bis-(hydroxymethyl)furan (BHMF) has received relatively little attention so far. Similarly to FDCA, BHMF is a biobased platform chemical derived from renewable sources such as sugars. This review highlights different polymerization techniques for BHMF-based polyesters and addresses BHMF's relative instability during the synthesis of BHMF-derived polymers, including polycarbonates and polyurethanes. Furthermore, the degradability of furanic polyesters is discussed and BHMF's toxicity is briefly elaborated.
引用
收藏
页码：8991 / 9003
页数：13
相关论文
共 50 条
[31]   Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan [J].
Zexing Huang ;
Zhijuan Zeng ;
Xiaoting Zhu ;
Wenguang Zhao ;
Jing Lei ;
Qiong Xu ;
Yongjun Yang ;
Xianxiang Liu .
Frontiers of Chemical Science and Engineering, 2023, 17 (04) :415-424
[32]   One-Pot Chemobiocatalytic Production of 2,5-Bis(hydroxymethyl)furan and Its Diester from Biomass in Aqueous Media [J].
Wu, Qian ;
Zong, Min-Hua ;
Li, Ning .
ACS CATALYSIS, 2023, 13 (14) :9404-9414
[33]   Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan [J].
Zexing Huang ;
Zhijuan Zeng ;
Xiaoting Zhu ;
Wenguang Zhao ;
Jing Lei ;
Qiong Xu ;
Yongjun Yang ;
Xianxiang Liu .
Frontiers of Chemical Science and Engineering, 2023, 17 :415-424
[34]   Insight into the catalytic mechanism of CuCeOx/C x /C for the hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan [J].
Bian, Jianfei ;
Li, Xiaokai ;
Jia, Wenlong ;
Li, Zheng ;
Tang, Xing ;
Zeng, Xianhai ;
Lin, Lu ;
Jiang, Wei ;
Peng, Lincai ;
Sun, Yong .
MOLECULAR CATALYSIS, 2024, 561
[35]   Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni-Ga intermetallic catalysts and its kinetic studies [J].
Sun, Weixiao ;
Zhong, Fuzeyu ;
Ge, Xiaohu ;
Chen, Wenyao ;
Qian, Gang ;
Cao, Yueqiang ;
Duan, Xuezhi ;
Zhou, Xinggui ;
Zhang, Jing .
REACTION CHEMISTRY & ENGINEERING, 2024, 9 (07) :1796-1804
[36]   A Light(er) Approach for the Selective Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan without External H2 [J].
Jaryal, Arpna ;
Venugopala Rao, Battula ;
Kailasam, Kamalakannan .
CHEMSUSCHEM, 2022, 15 (13)
[37]   Improved Bio-Synthesis of 2,5-bis(hydroxymethyl)furan by Burkholderia contaminans NJPI-15 With Co-substrate [J].
Chang, Siyuan ;
He, Xuejun ;
Li, Bingfeng ;
Pan, Xin .
FRONTIERS IN CHEMISTRY, 2021, 9
[38]   Efficient and Selective Electrochemical and Photoelectrochemical Reduction of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan using Water as the Hydrogen Source [J].
Roylance, John J. ;
Kim, Tae Woo ;
Choi, Kyoung-Shin .
ACS CATALYSIS, 2016, 6 (03) :1840-1847
[39]   Efficient reduction of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl) furan by Bacillus subtilis HA70 whole cells [J].
Xia, Jun ;
Jiang, Shenqi ;
Liu, Jingyi ;
Yang, Wei ;
Qiu, Zhongyang ;
Liu, Xiaoyan ;
He, Aiyong ;
Li, Dengchao ;
Xu, Jiaxing .
MOLECULAR CATALYSIS, 2023, 542
[40]   Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl) Furan over Ru/Co3O4 [J].
Wang, Ting ;
Zhang, Junhua ;
Xie, Wenxing ;
Tang, Yanjun ;
Guo, Daliang ;
Ni, Yonghao .
CATALYSTS, 2017, 7 (03)
12345