Addition of Alcohols to 4-Methylene-1,3-dioxolanes

被引：1
|
作者：
Sokov, S. A. [1 ]
Borisova, Yu. G. [1 ]
Raskil'dina, G. Z. [1 ]
Zlotsky, S. S. [1 ]
Golovanov, A. A. [1 ]
机构：
[1] Ufa State Petr Technol Univ, Ufa 450064, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 10期
关键词：
4-methylene-1,4-dioxaspiro[4.5]decane; alcohols; acid catalysis; selectivity; stereochemistry; competitive reaction method; ACETALS; ETHERS;
D O I：
10.1134/S107036322310002X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The addition of alcohols to 2-methylene-1,4-dioxaspiro[4.5]decane under the conditions of CF3CO2H catalysis occurs with the selective formation of the corresponding alkoxy derivatives. The conditions that ensure preparative isolation of target compounds in 63-94% yields have been determined, and relative activity of alcohols in the addition reaction at the exocyclic double bond of substrates has been determined.
引用
收藏
页码：2493 / 2497
页数：5
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