Nitrogen K-edge X-ray adsorption near-edge structure spectroscopy of chemically adsorbed ammonia gas on clay minerals and the 15N/14N-nitrogen isotopic fractionation

被引：0
作者：
Sugahara, Haruna [1 ,2 ]
Yoshimura, Toshihiro [1 ]
Tamenori, Yusuke [3 ,4 ]
Takano, Yoshinori [1 ]
Ogawa, Nanako O. [1 ]
Chikaraishi, Yoshito [1 ,5 ]
Ohkouchi, Naohiko [1 ]
机构：
[1] Japan Agcy Marine Earth Sci & Technol JAMSTEC, Biogeochem Res Ctr BGC, Yokosuka, Kanagawa 2370061, Japan
[2] Japan Aerosp Explorat Agcy JAXA, Inst Space & Astronaut Sci ISAS, 3-1-1 Yoshinodai,Chuo Ku, Sagamihara, Kanagawa 2525210, Japan
[3] Japan Synchrotron Radiat Res Inst, SPring-8,1-1-1 Kouto, Sayo, Hyogo 6795198, Japan
[4] Tokyo Metropolitan Univ, Org Res Promot, 1-1 Hachioji, Tokyo 1920397, Japan
[5] Hokkaido Univ, Inst Low Temp Sci, Sapporo, Hokkaido 0600819, Japan
来源：
ANALYTICAL SCIENCES | 2024年 / 40卷 / 04期
基金：
日本学术振兴会;
关键词：
Ammonia; Nitrogen isotopic fractionation; XANES; Adsorption; Clay mineral;
D O I：
10.1007/s44211-023-00503-5
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Ammonia (NH3) is a simple and essential nitrogen carrier in the universe. Its adsorption on mineral surfaces is an important step in the synthesis of nitrogenous organic molecules in extraterrestrial environments. The nitrogen isotopic ratios provide a useful tool for understanding the formation processes of N-bearing molecules. In this study, adsorption experiments were conducted using gaseous NH3 and representative clay minerals. The strongly adsorbed NH3 was N-15-enriched in a state of chemical equilibrium between the adsorption and desorption on the siliceous host surface. The nitrogen K-edge X-ray adsorption near-edge structure spectroscopy study revealed that these initial ammonia gases were chemically adsorbed as ammonium ions (NH4+) on clay minerals.
引用
收藏
页码：781 / 789
页数：9
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