Detachable Porous Organic Polymers Responsive to Light and Heat

被引：20

作者：

Diao, Ze-Jiu ^{[1
]}

Liu, Si-Yi ^{[1
]}

Wen, Hui ^{[1
]}

Liu, Guoliang ^{[1
]}

Yang, Tao ^{[1
]}

Li, Jing-Jing ^{[1
]}

Liu, Xiao-Qin ^{[1
]}

Sun, Lin-Bing ^{[1
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2023年 / 62卷 / 21期

基金：

中国国家自然科学基金;

关键词：

Adsorptive Separation; Anthracene; Detachable Porous Organic Polymers; Stimuli-Responsive Materials; DESIGN; CONVERSION; FRAMEWORK;

D O I：

10.1002/anie.202301739

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stimuli-responsive porous materials have captured much attention due to the on-demand tunable properties. Most reported stimuli-responsive porous materials are based on molecule isomerism or host-guest interaction, and it is highly desired to develop new types based on different responsive mechanism. Herein, inspired by natural cells which have the ability to fuse and divide induced by external stimulation, we report a new type of stimuli-responsive porous material based on detachment mechanism. A detachable porous organic polymer, namely DT-POP-1, is fabricated from the polymerization of anthracene-containing monomer (AnMon) when irradiated by 365 nm UV light. DT-POP-1 can detach into the monomer AnMon when irradiated with 275 nm UV light or heat. Such polymerization/detachment is reversible. The detachment results in a big difference in porosity and adsorption capacity, making the present detachable porous polymer highly promising in adsorptive separation and drug delivery.

引用

页数：5

共 30 条

[1] Post-Synthetically Elaborated BODIPY-Based Porous Organic Polymers (POPs) for the Photochemical Detoxification of a Sulfur Mustard Simulant [J].

Atilgan, Ahmet ;

Cetin, M. Mustafa ;

Yu, Jierui ;

Beldjoudi, Yassine ;

Liu, Jian ;

Stern, Charlotte L. ;

Cetin, Furkan M. ;

Islamoglu, Timur ;

Farha, Omar K. ;

Deria, Pravas ;

Stoddart, J. Fraser ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (43) :18554-18564

[2] Switching in Metal-Organic Frameworks [J].

Bigdeli, Fahime ;

Lollar, Christina T. ;

Morsali, Ali ;

Zhou, Hong-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (12) :4652-4669

[3] De novo design of tunable, pH-driven conformational changes [J].

Boyken, Scott E. ;

Benhaim, Mark A. ;

Busch, Florian ;

Jia, Mengxuan ;

Bick, Matthew J. ;

Choi, Heejun ;

Klima, Jason C. ;

Chen, Zibo ;

Walkey, Carl ;

Mileant, Alexander ;

Sahasrabuddhe, Aniruddha ;

Wei, Kathy Y. ;

Hodge, Edgar A. ;

Byron, Sarah ;

Quijano-Rubio, Alfredo ;

Sankaran, Banumathi ;

King, Neil P. ;

Lippincott-Schwartz, Jennifer ;

Wysocki, Vicki H. ;

Lee, Kelly K. ;

Baker, David .

SCIENCE, 2019, 364 (6441) :658-+

[4]

CHEN K, 2022, CHEM SOC REV, V14, P13904

[5] Efficient separation of xylene isomers by a guest-responsive metal-organic framework with rotational anionic sites [J].

Cui, Xili ;

Niu, Zheng ;

Shan, Chuan ;

Yang, Lifeng ;

Hu, Jianbo ;

Wang, Qingju ;

Lan, Pui Ching ;

Li, Yijian ;

Wojtas, Lukasz ;

Ma, Shengqian ;

Xing, Huabin .

NATURE COMMUNICATIONS, 2020, 11 (01)

[6] Azobenzene-Equipped Covalent Organic Framework: Light-Operated Reservoir [J].

Das, Gobinda ;

Prakasam, Thirumurugan ;

Addicoat, Matthew A. ;

Sharma, Sudhir Kumar ;

Rayaux, Florent ;

Mathew, Renny ;

Baias, Maria ;

Jagannathan, Ramesh ;

Olson, Mark A. ;

Trabolsi, Ali .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (48) :19078-19087

[7] Carbon capture and conversion using metal-organic frameworks and MOF-based materials [J].

Ding, Meili ;

Flaig, Robinson W. ;

Jiang, Hai-Long ;

Yaghi, Omar M. .

CHEMICAL SOCIETY REVIEWS, 2019, 48 (10) :2783-2828

[8] Energy Manipulation in Lanthanide-Doped Core-Shell Nanoparticles for Tunable Dual-Mode Luminescence toward Advanced Anti-Counterfeiting [J].

Ding, Mingye ;

Dong, Bang ;

Lu, Yi ;

Yang, Xiaofei ;

Yuan, Yongjun ;

Bai, Wangfeng ;

Wu, Shiting ;

Ji, Zhenguo ;

Lu, Chunhua ;

Zhang, Kan ;

Zeng, Haibo .

ADVANCED MATERIALS, 2020, 32 (45)

[9] Tuning the Electric Field Response of MOFs by Rotatable Dipolar Linkers [J].

Duerholt, Johannes P. ;

Jahromi, Babak Farhadi ;

Schmid, Rochus .

ACS CENTRAL SCIENCE, 2019, 5 (08) :1440-1448

[10] Design and control of gas diffusion process in a nanoporous soft crystal [J].

Gu, Cheng ;

Hosono, Nobuhiko ;

Zheng, Jia-Jia ;

Sato, Yohei ;

Kusaka, Shinpei ;

Sakaki, Shigeyoshi ;

Kitagawa, Susumu .

SCIENCE, 2019, 363 (6425) :387-+

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