UCl3 synthesis in molten LiCl-KCl and NaCl-MgCl2 via galvanically coupled uranium oxidation and FeCl2 reduction

被引：3

作者：

Yankey, Jacob ^{[1
]}

Chamberlain, Jarom ^{[1
]}

Monreal, Marisa ^{[2
]}

Jackson, Matt ^{[2
]}

Simpson, Michael ^{[1
]}

机构：

[1] Univ Utah, Mat Sci & Engn Dept, 122 S Cent Campus Dr 304, Salt Lake City, UT 84112 USA

[2] Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2023年 / 332卷 / 06期

基金：

欧洲研究理事会;

关键词：

Molten salt; Pyroprocessing; Molten salt reactor; Electrochemistry; Electrorefining; TRICHLORIDE;

D O I：

10.1007/s10967-023-08866-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Molten salt mixtures containing LiCl-KCl and NaCl-MgCl2 have been infused with UCl3 via reaction of U metal and FeCl2. The process starts with base salt (LiCl-KCl or NaCl-MgCl2) drying/purification using hydrochlorination via bubbling anhydrous HCl. An auto-titrator running in pH-stat mode was used to determine the point at which there is no net reaction with the salt. U metal is contained in a porous stainless steel basket as it is submerged in the molten salt. The byproduct Fe metal forms dendrites on the basket walls, allowing for simple separation from the molten salt. Based on analysis of salt samples using inductively coupled plasma mass spectroscopy, UCl3 yield of 90% was attained in both NaCl-MgCl2 at 550 degrees C and in LiCl-KCl at 450 degrees C. Open circuit potential difference between a W rod working electrode and a Ag/AgCl reference electrode indicated a UCl4 to UCl3 activity ratio of 1 x 10(-5). The iron dendrites were comprised of linked cubic structures with length scale of about 50 mu m.

引用

页码：2317 / 2328

页数：12