Coherent transient exciton transport in disordered polaritonic wires

被引:11
作者
Aroeira, Gustavo J. R. [1 ,2 ]
Kairys, Kyle T. [1 ,2 ]
Ribeiro, Raphael F. [1 ,2 ]
机构
[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA
[2] Emory Univ, Cherry Emerson Ctr Sci Computat, Atlanta, GA 30322 USA
关键词
polaritons; exciton transport; energetic disorder; ENERGY-TRANSFER; DYES;
D O I
10.1515/nanoph-2023-0797
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Excitation energy transport can be significantly enhanced by strong light-matter interactions. In the present work, we explore intriguing features of coherent transient exciton wave packet dynamics on a lossless disordered polaritonic wire. Our main results can be understood in terms of the effective exciton group velocity, a new quantity we obtain from the polariton dispersion. Under weak and moderate disorder, we find that the early wave packet spread velocity is controlled by the overlap of the initial exciton momentum distribution and its effective group velocity. Conversely, when disorder is stronger, the initial state is nearly irrelevant, and red-shifted cavities support excitons with greater mobility. Our findings provide guiding principles for optimizing ultrafast coherent exciton transport based on the magnitude of disorder and the polariton dispersion. The presented perspectives may be valuable for understanding and designing new polaritonic platforms for enhanced exciton energy transport.
引用
收藏
页码:2553 / 2564
页数:11
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