Applications of Polymethylhydrosiloxane (PMHS) in Organic Synthesis-Covering up to March 2022

被引：17

作者：

Alam, Mohammed Mujahid ^{[1
]}

Seema, Vittal ^{[2
]}

Dubasi, Narsimhaswamy ^{[3
]}

Kurra, Mohan ^{[4
]}

Varala, Ravi ^{[5
,6
]}

机构：

[1] King Khalid Univ, Coll Sci, Dept Chem, POB 9004, Abha 61413, Saudi Arabia

[2] RGUKT Basar, Dept Chem, Nirmal 504107, Telangana, India

[3] 12001 Belcher Rd S,Apt N226, Largo, FL 33773 USA

[4] Telangana Univ, Dept Pharmaceut Chem, Nizamabad 503322, Telangana, India

[5] Scrips Pharma, Hyderabad 500076, Telangana, India

[6] Scrips Pharma, Hyderabad 76, Telangana, India

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2023年 / 20卷 / 07期

关键词：

PMHS; transition metal; catalysis; organic synthesis; applications; functional group conversions; environmental standards; REDUCTIVE AMINATION; CATALYTIC-REDUCTION; POLY METHYLHYDROSILOXANE; ASYMMETRIC-SYNTHESIS; CARBONYL-COMPOUNDS; TERTIARY AMIDES; N-FORMYLATION; KETONES; AMINES; HYDROSILYLATION;

D O I：

10.2174/1570193X20666221021104906

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on the type of metal or non-metal catalyst used, the authors of this paper have clearly highlighted the different applications of air-stable, commercially viable, and environmentally friendly polymethylhydrosiloxane (PMHS) in organic synthesis or other allied reactions. The importance of PMHS was emphasised for the particular organic transformation's success. In addition to its well-known use as a reducing agent, it has also been demonstrated in a variety of other applications, including ring cleavage, the cotton industry, functional material for microfluidic chips, and the dehydroaromatization of bio-oils. The article tries to compile the most noteworthy cases of highly successful PMHS catalysis over the past two decades or so.

引用

页码：708 / 734

页数：27

共 63 条

[1] Hydrosilane and bismuth-accelerated palladium catalyzed aerobic oxidative esterification of benzylic alcohols with air [J].